Thin strip of amorphous alloy, nanocrystal soft magnetic alloy, and magnetic core
View Patent ↗Disclosed are a thin strip of an amorphous alloy having excellent workability, a nanocrystalline soft magnetic alloy which can stably provide good magnetic properties, and a magnetic core using the nanocrystalline soft magnetic alloy. The thin strip of an amorphous alloy is characterized in that the thin strip is formed of an alloy having a composition represented by Fe 100-a-b-c-d M a Si b B c Cu d (atomic %), wherein 0≦a≦10, 0≦b≦20, 4≦c≦20, 0.1≦d≦3, and 9≦a+b+c≦35, and containing unavoidable impurities, and, in the composition, M represents at least one element selected from Ti, V, Zr, Nb, Mo, Hf, Ta, and W, a Cu segregated part is present, on the surface side of the thin strip of the amorphous alloy, in which Cu is segregated at a higher concentration than the Cu concentration in the outermost surface part of the thin strip of the amorphous alloy, and the highest Cu concentration in the Cu segregated part is not more than 4 atomic %.
1. A nanocrystalline soft magnetic alloy comprising an annealed alloy ribbon made of an amorphous alloy having a composition represented by Fe 100-a-b-c-d M a Si b B c Cu d (wherein 0 at. %≦a≦10 at. %, 0 at. %≦b≦20 at. %, 4 at. %≦c≦20 at. %, 0.1 at. %≦d≦3 at. %, and 9 at. %≦a+b+c≦35 at. %) and inevitable impurities, wherein M in the alloy composition comprises at least one element selected from Ti, V, Zr, Nb, Mo, Hf, Ta and W;
the nanocrystalline soft magnetic alloy further comprising: a crystalline grain which has an average grain diameter of 50 nm or less, exists in a volume ratio of 50% or more, and has a Cu-segregated portion in which Cu is segregated at a position deeper than 2 nm from the surface of the annealed alloy ribbon, wherein a Cu concentration in the Cu-segregated portion is higher than Cu concentrations on the outermost surface of the annealed alloy ribbon and at a depth position of 500 nm from the surface of the annealed alloy ribbon, and a maximum value of the Cu concentration in the Cu-segregated portion is 6 at. % or less by measurement of Glow Discharge Optical Emission Spectroscopy (GDOES); and a region in which the Cu concentration is lower than the Cu concentration in a parent phase at a position deeper than the Cu-segregated portion, and a minimum value of the Cu concentration in the region is less than 40% of the Cu concentration in the parent phase; and
wherein an oxygen concentration at a position of 12 nm from the surface of the annealed alloy ribbon is higher than a Fe concentration thereat therein.
2. The nanocrystalline soft magnetic alloy according to claim 1 , wherein the maximum value of the Cu concentration in the Cu-segregated portion is two or more times the Cu concentration in the parent phase.
3. A magnetic core, comprising the nanocrystalline soft magnetic alloy according to claim 1 .