Low-thermal-expansion Ni-based super-heat-resistant alloy for boiler and having excellent high-temperature strength, and boiler component and boiler component production method using the same
View Patent ↗Disclosed is a low-thermal-expansion Ni-based super-heat-resistant alloy for a boiler, which has excellent high-temperature strength. The alloy can be welded without the need of carrying out any aging treatment. The alloy has a Vickers hardness value of 240 or less. The alloy comprises (by mass) C in an amount of 0.2% or less, Si in an amount of 0.5% or less, Mn in an amount of 0.5% or less, Cr in an amount of 10 to 24%, one or both of Mo and W in such an amount satisfying the following formula: Mo+0.5 W=5 to 17%, Al in an amount of 0.5 to 2.0%, Ti in an amount of 1.0 to 3.0%, Fe in an amount of 10% or less, and one or both of B and Zr in an amount of 0.02% or less (excluding 0%) for B and in an amount of 0.2% or less (excluding 0%) for Zr, with the remainder being 48 to 78% of Ni and unavoidable impurities.
1. A boiler component made of a low-thermal-expansion Ni-base superalloy, the superalloy consisting essentially of, by mass, not more than 0.2% C, not more than 0.5% Si, not more than 0.5% Mn, 10 to 24% Cr, at least one of Mo and W in an amount in terms of an equation of “Mo+0.5W”=5 to 17%, 0.5 to 2.0% Al, 1.0 to 3.0% Ti, not more than 10% Fe, and at least one of B and Zr in amounts of from exclusive zero to 0.02% B and from exclusive zero to 0.2% Zr, and the balance of Ni and unavoidable impurities,
wherein no precipitates of a γ′ phase having a size of not less than 20 nm exist in an alloy matrix of the Ni-base superalloy other than a weld portion and a heat affected zone by welding, and
wherein the superalloy other than the weld portion and the heat affected zone by welding has a Vickers hardness of not more than 240.
2. The boiler component according to claim 1 , wherein the superalloy consists essentially of, by mass, 0.005 to 0.15% C, 15 to 24% Cr, 1.2 to 2.5% Ti, not more than 5% Fe, at least one of B and Zr in amounts of 0.002 to 0.02% B and 0.01 to 0.2% Zr, and the balance of 48 to 78% Ni and unavoidable impurities.
3. The boiler component according to claim 1 , wherein the superalloy consists essentially of, by mass, 0.5 to 1.7% Al, 1.2 to 1.8% Ti, not more than 2% Fe, and 50 to 70% Ni.
4. The boiler component according to claim 1 , wherein a value defined by an equation of Al/(Al+0.56Ti) is 0.45 to 0.70.
5. A method of producing a boiler component made of the Ni-base superalloy as defined in claim 1 , comprising the steps of:
melting the Ni-base superalloy;
casting the molten Ni-base superalloy to obtain an ingot;
subjecting the ingot to plastic working of at least one of hot working and cold working; and
subjecting the worked product to solution heat treatment at a temperature of 980 to 1100° C., wherein an obtained final product as not aged has a Vickers hardness of not more than 240.