White light-emitting lamp for illumination and illuminating device using the same
A white light emitting lamp 1 includes a phosphor layer 5 which emits white light by being excited by light emitted from a semiconductor light emitting element 2 . A transparent resin layer 4 is interposed between the semiconductor light emitting element 2 and the phosphor layer 5 . The phosphor layer 5 contains, as a green phosphor, a rare earth borate phosphor activated by trivalent cerium and terbium.
1. A white light emitting lamp for illumination, comprising:
a semiconductor light emitting element which emits ultraviolet or violet light having a peak wavelength in a range of not less than 300 nm nor more than 430 nm;
a transparent resin layer disposed to cover at least a light emitting surface of the semiconductor light emitting element; and
a phosphor layer, disposed on the transparent resin layer, emitting white light by being excited by the ultraviolet or violet light emitted from the semiconductor light emitting element,
wherein the transparent resin layer is provided between the semiconductor light emitting element and the phosphor layer, and has a thickness from the light emitting surface of the semiconductor light emitting element to the phosphor layer in a range of not less than 0.4 mm nor more than 10 mm,
wherein the phosphor layer includes a green phosphor emitting green light by absorbing the ultraviolet or violet light, a blue phosphor emitting blue light by absorbing the ultraviolet or violet light, and a red phosphor emitting red light by absorbing the ultraviolet or violet light, and the transparent resin layer does not include the green, blue, and red phosphors, and
wherein the green phosphor comprises a rare earth borate phosphor activated by trivalent cerium and terbium having a composition represented by a general formula:
(R 1-x-y )Ce x Tb y BO 3
where, R represents at least one element selected from Sc, Y, La, Gd and Lu, and x and y are numbers satisfying 0.03<x<0.3 and 0.03<y<0.3.
2. The white light emitting lamp for illumination according to claim 1 ,
wherein the blue phosphor comprises at least one selected from a chlorophosphate phosphor activated by bivalent europium having a composition represented by a general formula:
(M1 1-x ,Eu x ) 10 (PO 4 ) 6 .Cl 2
where, M1 represents at least one element selected from Mg, Ca, Sr and Ba, and x is a number satisfying the condition of 0.001<x<0.5, and
an aluminate phosphor activated by bivalent europium having a composition represented by a general formula:
a (M2 1-x ,Eu x )O. b Al 2 O 3
where, M2 represents at least one element selected from Mg, Ca, Sr, Ba, Zn, Li, Rb and Cs, and a, b and x are numbers satisfying 0<a, 0<b, 0.2≦a/b≦1.5 and 0.001<x<0.5.
3. The white light emitting lamp for illumination according to claim 1 ,
wherein the red phosphor comprises a rare earth oxysulfide phosphor activated by europium having a composition represented by a general formula:
(A 1-x ,Eu x ) 2 O 2 S
where, A represents at least one element selected from La and Y, and x is a number satisfying 0.01<x<0.15.
4. The white light emitting lamp for illumination according to claim 1 ,
wherein the thickness of the transparent resin layer is in a range of not less than 1 mm nor more than 10 mm.
5. The white light emitting lamp for illumination according to claim 1 ,
wherein the transparent resin layer has a shape to cover the entire of the semiconductor light emitting element mounted on a substrate.
6. The white light emitting lamp for illumination according to claim 5 ,
wherein the transparent resin layer is formed in a hemispherical shape on the substrate to cover the entire of the semiconductor light emitting element.
7. The white light emitting lamp for illumination according to claim 1 ,
wherein the phosphor layer comprises a resin layer containing the green phosphor, the blue phosphor, and the red phosphor.
8. The white light emitting lamp for illumination according to claim 1 ,
wherein each of the green phosphor, the blue phosphor, and the red phosphor has a particle shape having an average particle diameter in a range of 1 μm or greater.
9. The white light emitting lamp for illumination according to claim 1 ,
wherein the semiconductor light emitting element comprises a light emitting diode or a laser diode.
10. An illuminating device, comprising:
the white light emitting lamp according to claim 1 .
11. The illuminating device according to claim 10 , further comprising:
a substrate; and
a plurality of the white light emitting lamps disposed on the substrate.
12. The illuminating device according to claim 11 ,
wherein the plurality of white light emitting lamps are disposed on the substrate in a matrix shape.
13. The illuminating device according to claim 11 ,
wherein the plurality of white light emitting lamps are linearly disposed on the substrate.
14. The white light emitting lamp for illumination according to claim 1 ,
wherein each of the green phosphor, the blue phosphor, and the red phosphor has a particle shape having an average particle diameter in a range of 10 μm or greater.
15. The white light emitting lamp for illumination according to claim 1 ,
wherein the phosphor layer includes the green phosphor in a range of 2 to 50 mass % to a total amount of the green, blue and red phosphor, the blue phosphor in a range of 2 to 50 mass % to the total amount of the green, blue and red phosphor, and balance of the red phosphor.