Toners for electrostatic-image development, cartridge employing toner for electrostatic-image development, and image-forming apparatus
View Patent ↗An object of the invention is to provide a toner which is effective in improving image quality while inhibiting white-background fouling, residual-image phenomenon (ghost), blurring (suitability for solid printing), and the like that occur depending on the proportion of a fine powder having a particle diameter not larger than a specific value, and which has satisfactory removability in cleaning, mitigates problems concerning fouling, etc. in long-term use even on a high-speed printer, and attains excellent image stability. Another object is to provide an image-forming apparatus and a toner cartridge each employing the toner. The invention provides a toner for electrostatic-image development satisfying all of the following (1) to (4) or a toner for electrostatic-image development which is a toner containing a charge control agent and satisfying all of the following (5) to (7). The invention further provides an image-forming apparatus and a toner cartridge each employing the toner. (1) To have a volume-median diameter (Dv50) of from 4.0 μm to 7.5 μm. (2) To have an average degree of circularity of 0.93 or higher. (3) A volume-median diameter (Dv50) of the toner and population number % of toner particles having a particle diameter of from 2.00 μm to 3.56 μm (Dns) in the toner satisfy the relationship Dns≦0.233 EXP(17.3/Dv50). (4) To have a coefficient of variation in number of 24.0% or lower. (5) To have a volume-median diameter (Dv50) of from 4.0 μm to 7.5 μm. (6) A volume-median diameter (Dv50) of the toner and population number % of toner particles having a particle diameter of from 2.00 μm to 3.56 μm (Dns) in the toner satisfy the relationship Dns≦0.233 EXP(17.3/Dv50). (7) When the charge control agent on the toner surface is cleaned, the resultant depressions have an average diameter of 500 nm or smaller.
1. A toner for electrostatic-image development satisfying all of the following (1) to (4):
(1) a volume-median diameter (Dv50) is from 4.0 μm to 7.5 μm;
(2) an average degree of circularity is 0.93 or higher;
(3) a volume-median diameter (Dv50) of the toner and population number % of toner particles having a particle diameter of from 2.00 vim to 3.56 μm (Dns) in the toner satisfy the relationship Dns≦0.233EXP(17.3/Dv50); and
(4) a coefficient of variation in number is 24.0% or lower.
2. The toner for electrostatic-image development according to claim 1 , wherein the volume-median diameter (Dv50) of the toner and population number % of toner particles having a particle diameter of from 2.00 μm to 3.56 μm (Dns) in the toner satisfy the relationship Dns≦0.11EXP(19.9/Dv50).
3. The toner for electrostatic-image development according to claim 1 , wherein the volume-median diameter (Dv50) of the toner and population number % of toner particles having a particle diameter of from 2.00 μm to 3.56 μm (Dns) in the toner satisfy the relationship 0.0517EXP(22.4/Dv50)≦Dns.
4. The toner for electrostatic-image development according to claim 1 , wherein the volume-median diameter (Dv50) of the toner is from 5.0 μm to 7.5 μm.
5. The toner for electrostatic-image development according to claim 1 , wherein the population number % of toner particles having a particle diameter of from 2.00 μm to 3.56 μm (Dns) is 6% by number or lower.
6. The toner for electrostatic-image development according to claim 1 , which is a toner obtained by forming particles in an aqueous medium.
7. The toner for electrostatic-image development according to claim 1 , which is a toner produced by an emulsion polymerization agglutination method.
8. The toner for electrostatic-image development according to claim 1 , which comprises core particles and fine resin particles bonded or adhered to the core particles.
9. The toner for electrostatic-image development according to claim 8 , wherein the fine resin particles contain a wax.
10. The toner for electrostatic-image development according to claim 8 or 9 , wherein the core particles each are constituted at least of primary polymer particles, and the total proportion of polar monomers in 100% by mass of all polymerizable monomers constituting a binder resin as the fine resin particles is lower than the total proportion of polar monomers in 100% by mass of all polymerizable monomers constituting a binder resin as the primary polymer particles constituting the core particles.
11. The toner for electrostatic-image development according to claim 1 , which comprises a wax in an amount of 4 to 20 parts by weight per 100 parts by weight of the toner for electrostatic-image development.
12. The toner for electrostatic-image development according to claim 1 , which is a color toner.
13. The toner for electrostatic-image development according to claim 12 , which has a surface potential of −30 V or lower.
14. The toner for electrostatic-image development according to claim 12 or 13 , where a solid print image has a gloss value of 32 or lower.
15. The toner for electrostatic-image development according to claim 1 , which is obtained without via a step for removing particles not larger than the volume-median diameter (Dv50) of the toner.
16. The toner for electrostatic-image development according to claim 1 , which has a standard deviation of charge amount of from 1.0 to 2.0.