Dielectric coating for single sided back contact solar cells
View Patent ↗A dielectric coating material system for use in a single-sided back contact solar cell is disclosed. The material system serves to electrically isolate electrodes of opposite polarity types on the same side of a silicon-based solar cell, and includes titanium and phosphorus.
1. A printable dielectric coating material system comprising phosphorus and a metal selected from the group consisting of titanium, tantalum, and niobium, said material system comprising about 0.1 to about 10 wt % of the metal, wherein the phosphorus is provided as an ester.
2. The material system of claim 1 , wherein the phosphorus is provided as a phosphate ester of an alkoxylated alcohol, alkoxylated phenol, or a combination thereof.
3. The material system of claim 2 , wherein the alkoxylated alcohol or alkoxylated phenol is selected from the group consisting of alkoxylated oleyl alcohol, alkoxylated phenol, alkoxylated dinonylphenol, alkoxylated didecylphenol, and combinations thereof.
4. The material system of claim 2 , wherein the alkoxylated alcohol or alkoxylated phenol is an ethoxylated alcohol or ethoxylated phenol selected from the group consisting of ethoxylated oleyl alcohol, ethoxylated phenol, ethoxylated dinonylphenol, ethoxylated didecylphenol, and combinations thereof.
5. The material system of claim 1 , wherein the phosphorus is provided as a phosphate ester of an alkoxide group or an ethoxide group.
6. The material system of claim 1 , wherein the ester is an alkoxylated phosphate ester.
7. The material system of claim 1 , wherein the ester is an ethoxylated phosphate ester.
8. The printable dielectric coating material system of claim 1 , wherein the material system is devoid of barium.
9. The printable dielectric coating material system of claim 1 , wherein the phosphorus is present in an amount of about 0.1 to about 5 wt %, based upon the total weight of the material system.
10. The printable dielectric coating material system of claim 9 , wherein the phosphorous is present in an amount of about 0.2 to about 4 wt. %, based upon the total weight of the material system.
11. The printable dielectric coating material system of claim 10 , wherein the phosphorous is present in an amount of about 0.3 to about 2.5 wt. %, based upon the total weight of the material system.
12. A method of making a dielectric composition for use in a solar cell comprising:
a. providing a liquid phosphorus-containing composition,
b. contacting an organometallic compound with a dispersant to thoroughly wet the organometallic compound, and
c. combining and mixing the phosphorus-containing composition with the organometallic compound and at least one of a vehicle, a surfactant, and a solvent to form a dielectric paste mixture, wherein the organometallic compound includes a metal selected from the group consisting of titanium, tantalum, and niobium.
13. The method of claim 12 , wherein the liquid phosphorus-containing compound is filtered.
14. The method of claim 12 , wherein in (c), a glass frit is further combined and mixed with the phosphorus-containing compound and organometallic compound.
15. The method of claim 12 , wherein no metal implement comes into contact with any composition, compound, dispersant, vehicle, surfactant, solvent or paste at any time.