Production methods for solubilized lignin, saccharide raw material and monosaccharide raw material, and solubilized lignin
View Patent ↗A new lignin degradation product, a method for producing the same, and methods for producing a saccharide raw material and a monosaccharide raw material are provided. The method for producing the new lignin degradation product includes: (a first step) mixing 100 parts by mass of a powder, obtained by pulverizing a lignocellulosic raw material and defatting the resulting powder with an organic solvent, with aqueous hydrogen peroxide in an amount of 20 to 400 parts by mass in terms of hydrogen peroxide and heating the mixture for 5 to 120 minutes at a pressure of 0.1 to 1.5 MPa and a temperature of 80 to 200° C. while irradiating the mixture with microwaves; (a second step) separating insoluble matter from the aqueous hydrogen peroxide; (a third step) extracting the insoluble matter with a solvent to produce an extract; and (a fourth step) distilling the solvent away from the extract to yield a solubilized lignin as a residue. Further, a saccharide raw material composed mainly of a polysaccharide or a monosaccharide raw material is obtained by subjecting the liquid portion or the insoluble matter, respectively, obtained in the first step to a predetermined treatment.
1. A production method of a solubilized lignin, comprising:
a first step of mixing 100 parts by mass (on a dry basis) of a powder obtained by pulverizing a lignocellulosic raw material with aqueous hydrogen peroxide in an amount of 20 to 400 parts by mass in terms of hydrogen peroxide and heating the mixture for 5 to 120 minutes at a pressure of 0.1 to 1.5 MPa and a temperature of 80 to 200° C. while irradiating the mixture with microwaves;
a second step of separating insoluble matter obtained in the first step from the aqueous hydrogen peroxide;
a third step of extracting the insoluble matter obtained in the second step with a solvent to produce an extract; and
a fourth step of distilling the solvent away from the extract obtained in the third step to yield a residue.
2. The production method of a solubilized lignin according to claim 1 , wherein the solvent used in the third step is an acetone-water mixed solve.
3. A production method of a saccharide raw material, comprising:
a first step of mixing 100 parts by mass (on a dry basis) of a powder obtained by pulverizing a lignocellulosic raw material with aqueous hydrogen peroxide in an amount of 20 to 400 parts by mass in terms of hydrogen peroxide and heating the mixture for 5 to 120 minutes at a pressure of 0.1 to 1.5 MPa and a temperature of 80 to 200° C. while irradiating the mixture with microwaves;
a second step of separating insoluble matter obtained in the first step to obtain a liquid portion; and
a third step of removing hydrogen peroxide in the liquid portion obtained in the second step.
4. A production method of a monosaccharide raw material, comprising:
a. first step of mixing 100 parts by mass (on a dry basis) of a powder obtained by pulverizing a lignocellulosic raw material with aqueous hydrogen peroxide in an amount of 20 to 400 parts by mass in terms of hydrogen peroxide and heating the mixture for 5 to 120 minutes at a pressure of 0.1 to 1.5 MPa and a temperature of 80 to 200° C. while irradiating the mixture with microwaves;
a second step of separating insoluble matter obtained in the first step from the aqueous hydrogen peroxide;
a third step of extracting the insoluble matter obtained in the second step with a solvent to produce an extraction residue; and
a fourth step of adding hydrogen peroxide to the extraction residue obtained in the third step followed by reirradiation with microwaves, or adding a strong acid to the extraction residue followed by heating, to obtain soluble matter.