Palladium-gold catalyst synthesis
A supported palladium-gold catalyst is produced under mild conditions using a commonly available base, such as sodium hydroxide (NaOH) or sodium carbonate (Na 2 CO 3 ). In this method, support materials and a base solution are mixed together and the temperature of the mixture is increased to a temperature above room temperature. Then, palladium salt and gold salt are added to the mixture while maintaining the pH of the mixture to be greater than 7.0 and keeping the mixture at a temperature above room temperature. This is followed by cooling the mixture while adding acetic acid to maintain the pH of the mixture to be within a desired pH range, filtering out the supported palladium-gold particles, washing with a pH buffer solution and calcining.
1. A method for producing a supported catalyst containing palladium-gold metal particles, comprising the steps of:
preparing a mixture of support materials and a solution that is basic and having a pH that is greater than 9.0;
adding a palladium salt solution and a gold salt solution, which have been separately prepared, to the mixture while maintaining the pH of the mixture to be greater than 7.0;
heating the mixture and maintaining the mixture at 343 K to 369 K above room temperature for a period of time; and
cooling the mixture and, while cooling, maintaining the pH of the mixture to be between 7.7 and 8.1.
2. The method according to claim 1 , wherein the pH of the mixture, while cooling, is maintained by adding acetic acid.
3. The method according to claim 1 , wherein the pH of the mixture is maintained between 8.5 and 11.0 while the palladium salt solution and the gold salt solution are added.
4. The method according to claim 1 , wherein the pH of the mixture is maintained between 10.0 and 10.5 while the palladium salt solution and the gold salt solution are added.
5. The method according to claim 1 , wherein the palladium and gold salt solutions are added dropwise to the mixture simultaneously.
6. The method according to claim 1 , further comprising:
filtering the mixture to separate out the supported catalyst; and
washing the supported catalyst with a pH buffer solution.
7. The method according to claim 6 , wherein the pH buffer solution comprises ammonium bicarbonate.
8. The method according to claim 6 , wherein the pH buffer solution comprises alkaline bicarbonate.
9. A method for producing a supported catalyst containing palladium-gold metal particles, comprising the steps of:
preparing a mixture of support materials and a solution that is basic and having a pH that is greater than 7.0;
adding a palladium salt solution and a gold salt solution, which have been separately prepared, to the mixture while maintaining the pH of the mixture to be greater than 7.0;
filtering the mixture to separate out the supported catalyst; and
washing the supported catalyst with a pH buffer solution including bicarbonates.
10. The method according to claim 9 , wherein the pH buffer solution comprises ammonium bicarbonate.
11. The method according to claim 9 , wherein the pH buffer solution comprises alkaline bicarbonate.
12. The method according to claim 11 , further comprising an additional washing step using water.
13. The method according to claim 9 , further comprising:
prior to the filtering step, heating the mixture and maintaining the mixture at 343 K to 369 K above room temperature for a period of time; and
cooling the mixture and, while cooling, maintaining the pH of the mixture to be between 7.7 and 8.1.
14. The method according to claim 13 , wherein the pH of the mixture is maintained by adding acetic acid.
15. The method according to claim 9 , further comprising, prior to the filtering step, maintaining the mixture at above room temperature for a period of time.
16. The method according to claim 15 , further comprising cooling the mixture and, while cooling, maintaining the pH of the mixture to be between 7.7 and 8.1.
17. The method according to claim 16 , wherein the pH of the mixture, while cooling, is maintained by adding acetic acid.
18. The method according to claim 17 , wherein the pH buffer solution comprises ammonium bicarbonate.
19. The method according to claim 17 , wherein the pH buffer solution comprises alkaline bicarbonate.