Triglyceride compositions useful for preparing composite panels and applications thereof
View Patent ↗Composite panels may be prepared using a moisture resistance additive having a formulation that includes a triglyceride having a saponification value of at least 150 and an iodine value of at least 35. The additive may be used in the form of a water emulsion. The water emulsion may be prepared by dispersing the components of the additive formulation under conditions sufficient to at least partially saponify the triglyceride. The moisture resistance additive can impart resistance to moisture absorption and thickness swelling to composite panels prepared therewith.
1. A composite panel prepared using a moisture resistance additive useful for preparing composite panels, the composite panel comprising:
gypsum, cellulose, or combinations thereof; and
the moisture resistance additive, wherein the moisture resistance additive is provided as an emulsion comprising:
from about 10 to about 50 weight percent of a triglyceride having a saponification value of at least 150 and an iodine value of at least 35;
from 0 to about 20 weight percent of a hydrocarbon wax;
from about 0.5 to about 3 weight percent of a linear C 12 to C 22 fatty acid;
a compound or compounds selected from the group consisting of an amine, an inorganic base, and mixtures thereof, and at least partially saponify the triglyceride, wherein the amine, when present, comprises from 0.5 to 3 weight percent of the emulsion, and wherein the inorganic base, when present, comprises from 0.5 to 6 weight percent of the emulsion;
from 0.5 to about 10 weight percent of at least one non-ionic emulsifier comprising a fatty acid ester of a polyalcohol; and
water.
2. The composite panel of claim 1 wherein the non-ionic emulsifier comprises sorbitan esters, or combinations of sorbitan esters, which exhibit a Hydrophilic-Lipophilic Balance of greater than 10.
3. The composite panel of claim 2 wherein the non-ionic emulsifier is selected from sorbitan monostearate, sorbitan isostearate, sorbitan laurate, sorbitan oleate, sorbitan aplmitat, sorbitan sesquioleate, sorbitan monoisostearate ethoxylate, sorbitan monolaurate ethoxylate, sorbitan monooleate ethoxylate, sorbitan monopalmitate ethoxylate, sorbitan monostearate ethoxylate, sorbitan tetraoleate ethoxylate, sorbitan tetrastearate ethoxylate, sorbitan tristearate ethoxylate, sorbitan hexastearate ethoxylate and combinations thereof.
4. The composite panel of claim 2 wherein the non-ionic emulsifier is a monostearate emulsifier selected from polyoxyethylene sorbitan monostearate, sorbitan monostearate and combinations thereof.
5. The composite panel of claim 1 wherein the moisture resistance additive is essentially free of hydrocarbon wax.
6. The composite panel of claim 1 , wherein the hydrocarbon wax is present in an amount from about 0.50 to about 20 weight percent of the emulsion.
7. A method for preparing composite panels, comprising:
introducing a moisture resistance additive into a wet panel production process, the moisture resistance additive is provided as an emulsion comprising:
from about 10 to about 50 weight percent of a triglyceride having a saponification value of at least 150 and an iodine value of at least 35;
from 0 to about 20 weight percent of a hydrocarbon wax;
from about 0.5 to about 3 weight percent of a linear C 12 to C 22 fatty acid;
a compound or compounds selected from the group consisting of an amine, an inorganic base, and mixtures thereof, and at least partially saponify the triglyceride, wherein the amine, when present, comprises from 0.5 to 3 weight percent of the emulsion, and wherein the inorganic base, when present, comprises from 0.5 to 6 weight percent of the emulsion;
from 0.5 to about 10 weight percent of at least one non-ionic emulsifier comprising a fatty acid ester of a polyalcohol; and
water.
8. The method of claim 7 wherein the non-ionic emulsifier comprises sorbitan esters, or combinations of sorbitan esters, which exhibit a Hydrophilic-Lipophilic Balance of greater than 10.
9. The method of claim 8 wherein the non-ionic emulsifier is selected from sorbitan monostearate, sorbitan isostearate, sorbitan laurate, sorbitan oleate, sorbitan aplmitat, sorbitan sesquioleate, sorbitan monoisostearate ethoxylate, sorbitan monolaurate ethoxylate, sorbitan monooleate ethoxylate, sorbitan monopalmitate ethoxylate, sorbitan monostearate ethoxylate, sorbitan tetraoleate ethoxylate, sorbitan tetrastearate ethoxylate, sorbitan tristearate ethoxylate, sorbitan hexastearate ethoxylate and combinations thereof.
10. The method of claim 8 wherein the non-ionic emulsifier is a monostearate emulsifier selected from polyoxyethylene sorbitan monostearate, sorbitan monostearate and combinations thereof.
11. The method of claim 7 wherein the moisture resistance additive is essentially free of hydrocarbon wax.
12. The method of claim 11 wherein the moisture resistance additive is introduced into the composite panel by applying the moisture resistance additive to a cellulose component used to make the composite panel.
13. The method of claim 7 wherein the hydrocarbon wax is present in an amount from about 0.50 to about 20 weight percent of the emulsion.
14. A moisture resistance additive in the form of an emulsion useful for preparing composite panels comprising:
from about 10 to about 50 weight percent of a triglyceride having a saponification value of at least 150 and an iodine value of at least 35;
from 0 to about 20 weight percent of a hydrocarbon wax;
from about 0.5 to about 3 weight percent of a linear C 12 to C 22 fatty acid;
a compound or compounds selected from the group consisting of an amine, an inorganic base, and mixtures thereof, wherein the amine, when present, comprises from 0.5 to 3 weight percent of the emulsion, and wherein the inorganic base, when present, comprises from 0.5 to 6 weight percent of the emulsion;
from 0.5 to about 10 weight percent of at least one non-ionic emulsifier comprising a fatty acid ester of a polyalcohol water.
15. The moisture resistance additive of claim 14 wherein the hydrocarbon wax is present in an amount from about 0.50 to about 20 weight percent of the emulsion.
16. The moisture resistance additive of claim 15 wherein the non-ionic emulsifier is selected from sorbitan monostearate, sorbitan isostearate, sorbitan laurate, sorbitan oleate, sorbitan aplmitat, sorbitan sesquioleate, sorbitan monoisostearate ethoxylate, sorbitan monolaurate ethoxylate, sorbitan monooleate ethoxylate, sorbitan monopalmitate ethoxylate, sorbitan monostearate ethoxylate, sorbitan tetraoleate ethoxylate, sorbitan tetrastearate ethoxylate, sorbitan tristearate ethoxylate, sorbitan hexastearate ethoxylate and combinations thereof.
17. The moisture resistance additive of claim 15 wherein the non-ionic emulsifier is a monostearate emulsifier selected from polyoxyethylene sorbitan monostearate, sorbitan monostearate and combinations thereof.
18. The moisture resistance additive of claim 15 wherein the emulsion is heated to a temperature sufficient to at least partially saponify the triglyceride.
19. The moisture resistance additive of claim 14 wherein the non-ionic emulsifier comprises sorbitan esters, or combinations of sorbitan esters, which exhibit a Hydrophilic-Lipophilic Balance of greater than 10.
20. The moisture resistance additive of claim 14 wherein the moisture resistance additive is essentially free of hydrocarbon wax.