System and method for softening water for use in a scrubber
View Patent ↗The present invention relates generally to the field of emission control equipment for boilers, heaters, kilns, or other flue gas-, or combustion gas-, generating devices (e.g., those located at power plants, processing plants) and, in particular to a new and useful method and apparatus designed to improve the water supplied to non-calcium-based, aqueous wet SO x scrubbers. In another embodiment, the present invention relates to a system and method for softening water for use in non-calcium-based, aqueous wet SO x scrubbers.
1. A system designed to treat and/or soften raw water supplied to a non-calcium-based, aqueous wet SO x scrubber, the system consisting essentially of:
(a) at least one floc supply means;
(b) at least one raw water supply means, wherein the raw water contains at least calcium ions and magnesium ions;
(c) at least one sodium carbonate supply means;
(d) at least one waste liquor supply means, wherein the waste liquor is supplied from a portion of the waste liquor generated by at least one non-calcium-based, aqueous wet SO x scrubber and wherein the waste liquor contains solubilized sulfite ions;
(e) at least one precipitator/crystallizer tank, wherein the at least one floc supply means, the at least one raw water supply means, the at least one sodium carbonate supply means and the at least one waste liquor supply means all supply their respective compounds to the at least one precipitator/crystallizer tank, and wherein the at least one precipitator/crystallizer tank permits and facilitates a reaction between the calcium ions and/or magnesium ions contained in the raw water, the sodium carbonate and the solubilized sulfite ions contained in the waste liquor supply and wherein the at least one precipitator/crystallizer tank has at least one outlet and is designed to remove any undesirable solids from the mixture of compounds supplied from the at least one floc supply means, the at least one raw water supply means, the at least one sodium carbonate supply means and the at least one waste liquor supply means so as to generate a treated solution of floc, sodium carbonate solution, raw water and waste liquor and supply same to the at least one outlet; and
(f) at least one settler/thickener tank that is in fluid communication with the at least one outlet of the at least one precipitator/crystallizer tank, the at least one settler/thickener tank having at least one outlet designed to supply treated water to a non-calcium-based, aqueous wet SO x scrubber,
wherein all of the solubilized sulfite ions necessary for the reaction between the calcium ions and/or magnesium ions contained in the raw water, the sodium carbonate and the solubilized sulfite ions are supplied from the waste liquor generated by the at least one non-calcium-based, aqueous wet SO x scrubber, and
wherein all of the calcium ions and/or magnesium ions necessary for the reaction between the calcium ions and/or magnesium ions contained in the raw water, the sodium carbonate and the solubilized sulfite ions are supplied from the raw water.
2. The system of claim 1 , further comprising:
(g) at least one treated water tank that is in fluid communication with the at least one outlet of the at least one settler/thickener tank, the at least one treated water tank designed to receive and hold treated water and having at least one outlet designed to supply treated water to a non-calcium-based, aqueous wet SO x scrubber.
3. The system of claim 1 , wherein less than about 7% by volume of the waste liquor produced by the non-calcium-based, aqueous wet SO x scrubber is supplied to the at least one waste liquor supply means to treat and/or soften raw water for a non-calcium-based, aqueous wet SO x scrubber.
4. The system of claim 1 , wherein less than about 5% by volume of the waste liquor produced by the non-calcium-based, aqueous wet SO x scrubber is supplied to the at least one waste liquor supply means to treat and/or soften raw water for a non-calcium-based, aqueous wet SO x scrubber.
5. The system of claim 1 , wherein less than about 3% by volume of the waste liquor produced by the non-calcium-based, aqueous wet SO x scrubber is supplied the at least one waste liquor supply means to treat and/or soften raw water for a non-calcium-based, aqueous wet SO x scrubber.
6. The system of claim 1 , wherein less than about 2% by volume of the waste liquor produced by the non-calcium-based, aqueous wet SO x scrubber is supply to the at least one waste liquor supply means to treat and/or soften raw water for a non-calcium-based, aqueous wet SO x scrubber.
7. The system of claim 1 , wherein the reaction that takes place in the at least one precipitator/crystallizer tank of element (e) is represented by the following chemical reaction: Ca +2 +CO 3 −2 +2Na + +SO 3 −2 →CaSO 3 (s)+2Na + +CO 3 −2 .
8. A system designed to treat and/or soften raw water supplied to a non-calcium-based, aqueous wet SO x scrubber, the system comprising:
(a) at least one floc supply means;
(b) at least one raw water supply means, wherein the raw water contains at least calcium ions and magnesium ions;
(c) at least one sodium carbonate supply means;
(d) at least one waste liquor supply means, wherein the waste liquor is supplied from a portion of the waste liquor generated by at least one non-calcium-based, aqueous wet SO x scrubber and wherein the waste liquor contains solubilized sulfite ions;
(e) at least one precipitator/crystallizer tank, wherein the at least one floc supply means, the at least one raw water supply means, the at least one sodium carbonate supply means and the at least one waste liquor supply means all supply their respective compounds to the at least one precipitator/crystallizer tank, and wherein the at least one precipitator/crystallizer tank permits and facilitates a reaction between the calcium ions and/or magnesium ions contained in the raw water, the sodium carbonate and the solubilized sulfite ions contained in the waste liquor supply and wherein the at least one precipitator/crystallizer tank has at least one outlet and is designed to remove any undesirable solids from the mixture of compounds supplied from the at least one floc supply means, the at least one raw water supply means, the at least one sodium carbonate supply means and the at least one waste liquor supply means so as to generate a treated solution of floc, sodium carbonate solution, raw water and waste liquor and supply same to the at least one outlet; and
(f) at least one settler/thickener tank that is in fluid communication with the at least one outlet of the at least one precipitator/crystallizer tank, the at least one settler/thickener tank having at least one outlet designed to supply treated water to a non-calcium-based, aqueous wet SO x scrubber,
wherein less than about 7% by volume of the waste liquor produced by the non-calcium-based, aqueous wet SO x scrubber is supplied to the at least one waste liquor supply means to treat and/or soften raw water for a non-calcium-based, aqueous wet SO x scrubber.
9. The system of claim 8 , further comprising:
(g) at least one treated water tank that is in fluid communication with the at least one outlet of the at least one settler/thickener tank, the at least one treated water tank designed to receive and hold treated water and having at least one outlet designed to supply treated water to a non-calcium-based, aqueous wet SO x scrubber.
10. The system of claim 8 , wherein less than about 5% by volume of the waste liquor produced by the non-calcium-based, aqueous wet SO x scrubber is supplied to the at least one waste liquor supply means to treat and/or soften raw water for a non-calcium-based, aqueous wet SO x scrubber.
11. The system of claim 8 , wherein less than about 3% by volume of the waste liquor produced by the non-calcium-based, aqueous wet SO x scrubber is supplied the at least one waste liquor supply means to treat and/or soften raw water for a non-calcium-based, aqueous wet SO x scrubber.
12. The system of claim 8 , wherein less than about 2% by volume of the waste liquor produced by the non-calcium-based, aqueous wet SO x scrubber is supply to the at least one waste liquor supply means to treat and/or soften raw water for a non-calcium-based, aqueous wet SO x scrubber.
13. The system of claim 8 , wherein the reaction that takes place in the at least one precipitator/crystallizer tank of element (e) is represented by the following chemical reaction: Ca +2 +CO 3 −2 +2Na + +SO 3 −2 →CaSO 3 (s)+2Na + +CO 3 −2 .