Method for manufacturing SOI substrate
View Patent ↗An object is to reduce occurrence of defective bonding between a base substrate and a semiconductor substrate even when a silicon nitride film or the like is used as a bonding layer. Another object is to provide a method for manufacturing an SOI substrate by which an increase in the number of steps can be suppressed. A semiconductor substrate and a base substrate are prepared; an oxide film is formed over the semiconductor substrate; the semiconductor substrate is irradiated with accelerated ions through the oxide film to form a separation layer at a predetermined depth from a surface of the semiconductor substrate; a nitrogen-containing layer is formed over the oxide film after the ion irradiation; the semiconductor substrate and the base substrate are disposed opposite to each other to bond a surface of the nitrogen-containing layer and a surface of the base substrate to each other; and the semiconductor substrate is heated to cause separation along the separation layer, thereby forming a single crystal semiconductor layer over the base substrate with the oxide film and the nitrogen-containing layer interposed therebetween.
1. A method for manufacturing an SOI substrate, comprising the steps of:
forming a silicon oxide film over a semiconductor substrate;
irradiating the semiconductor substrate with accelerated ions through the silicon oxide film to form a separation layer at a predetermined depth from a surface of the semiconductor substrate;
forming an oxide film over a base substrate;
forming a nitrogen-containing layer over the oxide film;
disposing the semiconductor substrate and the base substrate opposite to each other to bond a surface of the nitrogen-containing layer and a surface of the silicon oxide film to each other; and
heating the semiconductor substrate to cause separation along the separation layer, thereby forming a single crystal semiconductor layer over the base substrate with the oxide film and the nitrogen-containing layer interposed therebetween.
2. A method for manufacturing an SOI substrate, comprising the steps of:
irradiating a semiconductor substrate with accelerated ions to form a separation layer at a predetermined depth from a surface of the semiconductor substrate;
forming an oxide film over a base substrate;
forming a nitrogen-containing layer over the oxide film;
disposing the semiconductor substrate and the base substrate opposite to each other to bond a surface of the nitrogen-containing layer and the surface of the semiconductor substrate to each other; and
heating the semiconductor substrate to cause separation along the separation layer, thereby forming a single crystal semiconductor layer over the base substrate with the oxide film and the nitrogen-containing layer interposed therebetween.
3. The method for manufacturing an SOI substrate according to claim 1 , wherein the nitrogen-containing layer is formed by a plasma CVD method with introduction of a hydrogen gas at a substrate temperature equal to or higher than room temperature and equal to or lower than 350° C.
4. The method for manufacturing an SOI substrate according to claim 2 , wherein the nitrogen-containing layer is formed by a plasma CVD method with introduction of a hydrogen gas at a substrate temperature equal to or higher than room temperature and equal to or lower than 350° C.
5. The method for manufacturing an SOI substrate according to claim 3 , wherein the plasma CVD method is performed with introduction of a silane gas and an ammonia gas in addition to the hydrogen gas.
6. The method for manufacturing an SOI substrate according to claim 4 , wherein the plasma CVD method is performed with introduction of a silane gas and an ammonia gas in addition to the hydrogen gas.
7. The method for manufacturing an SOI substrate according to claim 1 , wherein the oxide film is formed by thermal oxidation treatment of the semiconductor substrate in an oxidizing atmosphere containing hydrogen chloride.
8. The method for manufacturing an SOI substrate according to claim 2 , wherein the oxide film is formed by thermal oxidation treatment of the semiconductor substrate in an oxidizing atmosphere containing hydrogen chloride.
9. The method for manufacturing an SOI substrate according to claim 1 further comprising performing pressurization treatment with a heat treatment after bonding the surface of the oxide film and the surface of the nitrogen-containing layer to each other.
10. The method for manufacturing an SOI substrate according to claim 2 further comprising performing pressurization treatment with a heat treatment after bonding the surface of the oxide film and the surface of the nitrogen-containing layer to each other.
11. The method for manufacturing an SOI substrate according to claim 1 , wherein a single crystal silicon substrate is used as the semiconductor substrate.
12. The method for manufacturing an SOI substrate according to claim 2 , wherein a single crystal silicon substrate is used as the semiconductor substrate.
13. The method for manufacturing an SOI substrate according to claim 1 , wherein a glass substrate having a surface with an average surface roughness of 0.3 nm or less is used as the base substrate.
14. The method for manufacturing an SOI substrate according to claim 2 , wherein a glass substrate having a surface with an average surface roughness of 0.3 nm or less is used as the base substrate.