Method of making a fiber optical cable assembly
View Patent ↗A process for forming a fiber optical cable assembly comprises the steps of (a) subjecting a first high tenacity reinforcement yarn such as para-aramid that is coated with a water-impermeable thermally reversible cross-linked polymeric coating to a temperature of from 45 to 200 ° C. for sufficient time to convert the protective coating via bond cleavage into a water-swellable super absorbent polymer, (b) combining one or more of the first reinforcement yarns from step (a) with one or more optical glass fiber transmission media and (c) applying a protective sleeve over at least one assembly of step (b).
1. A process for forming a fiber optical cable assembly comprising the steps of:
(a) subjecting a first reinforcement yarn having a linear density of from 150 to 12000 dtex, a tenacity of from 10 to 65 g/dtex, a modulus of from 150 to 2700 g/dtex, and an elongation to break of from 1 to 8 percent coated with a water-impermeable thermally reversible cross-linked polymeric precursor coating to a temperature of from 45 to 200° C. for sufficient time to convert the protective precursor coating via bond cleavage into a water-swellable super absorbent polymer, (b) combining one or more of the first reinforcement yarns from step (a) with one or more optical glass fiber transmission media and (c) applying a protective sleeve over at least one assembly of step (b),
wherein the precursor coating is a cross-linked polymer comprising reversible covalent bonds capable of bond cleavage under heat.
2. The process of claim 1 , wherein at least one second reinforcement yarn may optionally be combined with the first reinforcement yarns and glass fiber transmission media in step (b).
3. The process of claim 1 , wherein the polymer of the first reinforcement yarn is selected from the group consisting of p-aramid, polybenzazole, polypyridazole or mixtures thereof.
4. The process of claim 1 , wherein the thermally reversible cross-linkers of the thermally reversible coating are present in an amount of from 0.001% to 0.5% weight percent based on the total weight of first reinforcement yarn plus coating.
5. The process of claim 1 , wherein the thermally reversible cross-linked coating is present in the amount of from 0.1% to 10% weight percent based on the total weight of the first reinforcement yarn plus coating.
6. The process of claim 3 , wherein the p-aramid is poly(paraphenylene terephthalamide).
7. A fiber optic cable made by the process of claim 1 .
8. The process of claim 1 , wherein the coating comprises a blocked isocyanate, a Diels-Alder reaction product, an azo compound or mixtures thereof.