Non-lead glass
View Patent ↗To provide a glass containing little B 2 O 3 , whereby when its powder is fired, its thermal expansion curve does not have an inflection point, a non-lead glass is provided containing, as represented by mol % based on the following oxides, from 35 to 41.5% of SiO 2 , from 8 to 25% of MgO, more than 27 to 35% of CaO, from 0 to 2% of SrO, from 0 to 4% of BaO, from 5 to 15% of ZnO and from 4.5 to 10% of Al 2 O 3 , wherein the total content of these components is at least 97%, and when SrO and BaO are contained, the total content of SrO and BaO is at most 2%; as well as a non-lead glass containing, as represented by mol % based on the following oxides, from 39.5 to 41.5% of SiO 2 , from 10 to less than 13% of MgO, from 18 to 22% of CaO, more than 12 to 15% of SrO, from 0 to 1% of BaO, from 6 to 11% of ZnO and from 4.5 to 7% of Al 2 O 3 , wherein the total content of these components is at least 97%.
1. Non-lead glass comprising, as represented by mol % based on the following oxides, from 38 to 41.5% of SiO 2 , from 13 to 17% of MgO, 28 to 33% of CaO, from 0 to 2% of SrO, from 0 to 2.2% of BaO, from 5 to 12% of ZnO and from 4.5 to 7% of Al 2 O 3 , wherein the total content of these components is at least 97%, and when SrO and BaO are contained, the total content of SrO and BaO is at most 2%;
wherein the molar ratio of CaO to MgO is from 1.8 to 2.2.
2. The non-lead glass according to claim 1 , wherein BaO is from 0.8 to 1.2%, and from 0.8 to 1.2% of La 2 O 3 is contained.
3. The non-lead glass according to claim 1 , wherein SiO 2 is at most 41.2%.
4. The non-lead glass according to claim 1 , wherein an alkali metal oxide is not contained, or an alkali metal oxide is contained in the total amount of at most 1%.
5. The non-lead glass according to claim 1 , which has a softening point of higher than 800° C.
6. The non-lead glass according to claim 1 , wherein when its powder is fired at 950° C., a fired product obtained has an average linear expansion coefficient of from 90×10 −7 to 110×10 −7 /° C. at from 50 to 1,000° C.
7. The non-lead glass according to claim 1 , wherein when its powder is fired at from 900 to 1,100° C., CaO—MgO—SiO 2 crystal precipitates in a fired product obtained.
8. Sealing glass made of the non-lead glass as defined in claim 1 , which has a sealing temperature of at least 900° C.
9. A glass paste, which contains a powder of the non-lead glass as defined in claim 1 .
10. A green sheet, which contains a powder of the non-lead glass as defined in claim 1 .
11. A process for producing a solid oxide fuel cell, which comprises a step of sealing members made of a ceramics or metal each other by means of a powder of the non-lead glass as defined in claim 1 .
12. A solid oxide fuel cell having at least one sealed part at which members made of a ceramics or metal are sealed each other, wherein at least one sealed part is sealed with a fired product formed by firing the non-lead glass as defined in claim 1 .