Solar cell having silicon nano-particle emitter
View Patent ↗A silicon solar cell having a silicon substrate includes p-type and n-type emitters on a surface of the substrate, the emitters being doped nano-particles of silicon. To reduce high interface recombination at the substrate surface, the nano-particle emitters are preferably formed over a thin interfacial tunnel oxide layer on the surface of the substrate.
1. A silicon solar cell comprising:
a) a silicon substrate having first and second opposing major surfaces, wherein the first major surface is on a side of the solar cell which is configured to be disposed toward sunlight for creation of mobile carriers in the silicon substrate;
b) a thin interfacial passivation layer on the second major surface, wherein the thin interfacial passivation layer comprises a tunnel oxide layer; and
c) a plurality of emitters formed from doped silicon nano-particles, wherein the plurality of emitters are formed on the thin interfacial passivation layer on the second major surface, wherein the tunnel oxide layer is continuous under each emitter of the plurality of emitters.
2. The silicon solar cell of claim 1 wherein the substrate is polycrystalline silicon.
3. The silicon solar cell of claim 1 wherein the substrate is single crystalline silicon.
4. The silicon solar cell of claim 3 wherein the substrate is undoped.
5. The silicon solar cell of claim 3 wherein the substrate is lightly doped.
6. The silicon solar cell of claim 5 wherein the nano-particles of the emitters have a diameter of less than 20 nanometers.
7. The silicon solar cell of claim 1 , wherein the thin interfacial passivation layer covers the second major surface.