Nonaqueous electrolytic solution secondary battery
A nonaqueous electrolytic solution secondary battery includes a positive electrode, a negative electrode, and a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent. The nonaqueous solvent contains 80% by mass or more of a cyclic carbonate which does not have a carbon-carbon multiple bond and which does not contain a halogen and contains a cyclic sulfone compound having any one of structures represented by the following formulae (1) to (4): wherein each of R1 and R2 represents C m H 2m where 1≦m≦4. Also, each of R3 to R10 independently represents C n H 2n+1 where 1≦n≦4.
1. A nonaqueous electrolytic solution secondary battery comprising:
a positive electrode;
a negative electrode; and
a nonaqueous electrolytic solution having an electrolyte salt dissolved in a nonaqueous solvent, wherein
the nonaqueous solvent contains 80% by mass or more of a cyclic carbonate which does not have a carbon-carbon multiple bond and which does not contain a halogen, and contains a cyclic sulfone compound having any one of structures represented by the following formulae (1) to (4)
wherein each of R1 and R2 represents C m H 2m where 1≦m≦4 and each of R3 to R10 independently represents C n H 2n+1 where 1≦n≦4, and
wherein the cyclic carbonate which does not have a carbon-carbon multiple bond and which does not contain a halogen is at least one member selected from the group consisting of: ethylene carbonate, propylene carbonate, butylene carbonate and trimethylene carbonate.
2. The nonaqueous electrolytic solution secondary battery according to claim 1 , wherein
the cyclic carbonate which does not have a carbon-carbon multiple bond and which does not contain a halogen is at least one member selected from the group consisting of ethylene carbonate and propylene carbonate.
3. The nonaqueous electrolytic solution secondary battery according to claim 1 , wherein
a content of the cyclic sulfone compound in the nonaqueous solvent is 0.1% by mass or more and not more than 2.0% by mass.
4. The nonaqueous electrolytic solution secondary battery according to claim 1 , wherein
the nonaqueous solvent further contains a cyclic carbonate having a carbon-carbon multiple bond.
5. The nonaqueous electrolytic solution secondary battery according to claim 1 , wherein
the nonaqueous solvent further contains a halogenated cyclic carbonate.
6. The nonaqueous electrolytic solution secondary battery according to claim 1 , wherein
the nonaqueous solvent further contains a lactone.
7. The nonaqueous electrolytic solution secondary battery according to claim 1 , comprising an exterior member for housing made of a laminated film.
8. The nonaqueous electrolytic solution secondary battery according to claim 1 , wherein
the nonaqueous electrolytic solution is held by a polymer compound.
9. The nonaqueous electrolytic solution secondary battery according to claim 8 , wherein
the polymer compound is polyvinylidene fluoride or a copolymer thereof.
10. The nonaqueous electrolytic solution secondary battery according to claim 8 , wherein a content of the polymer compound ranges from 0.1% by mass to 10% by mass relative to a total mass of the electrolytic solution and the polymer compound.
11. The nonaqueous electrolytic solution secondary battery according to claim 8 , wherein the negative electrode comprises a negative electrode active material layer, and a thickness of the negative electrode active material layer ranges from 40 μm to 100 μm.
12. The nonaqueous electrolytic solution secondary battery according to claim 1 , wherein the sulfone compound has a structure represented by the following formulae (1) and (4)
wherein R1 represents C m H 2m where 1≦m≦4 and each of R7 to R10 independently represents C n H 2n+1 where 1≦n≦4.
13. The nonaqueous electrolytic solution secondary battery according to claim 1 , wherein the sulfone compound is 1,3-propanedisulfonic anhydride.
14. A nonaqueous electrolytic solution comprising:
an electrolyte salt dissolved in a nonaqueous solvent, wherein
the nonaqueous solvent contains 80% by mass or more of a cyclic carbonate which does not have a carbon-carbon multiple bond and which does not contain a halogen, and contains a cyclic sulfone compound having any one of structures represented by the following formulae (1) to (4)
wherein each of R1 and R2 represents C m H 2m where 1≦m≦4; and each of R3 to R10 independently represents C n H 2n+1 where 1≦n≦4 and
wherein the cyclic carbonate which does not have a carbon-carbon multiple bond and which does not contain a halogen is at least one member selected from the group consisting of: ethylene carbonate, propylene carbonate, butylene carbonate and trimethylene carbonate.
15. The nonaqueous electrolytic solution according to claim 14 , wherein
the cyclic carbonate which does not have a carbon-carbon multiple bond and which does not contain a halogen is at least one member selected from the group consisting of ethylene carbonate and propylene carbonate.