Composite materials formed with anchored nanostructures
View Patent ↗A method of forming nano-structure composite materials that have a binder material and a nanostructure fiber material is described. A precursor material may be formed using a mixture of at least one metal powder and anchored nanostructure materials. The metal powder mixture may be (a) Ni powder and (b) NiAl powder. The anchored nanostructure materials may comprise (i) NiAl powder as a support material and (ii) carbon nanotubes attached to nanoparticles adjacent to a surface of the support material. The process of forming nano-structure composite materials typically involves sintering the mixture under vacuum in a die. When Ni and NiAl are used in the metal powder mixture Ni 3 Al may form as the binder material after sintering. The mixture is sintered until it consolidates to form the nano-structure composite material.
1. A method of forming a nano-structure composite material having a binder material and a fiber material, comprising:
(a) forming a mixture comprising:
1. at least one powder, and
2. anchored nano-structured materials comprising (i) a metal powder support material, (ii) nanoparticles formed on a surface of the metal powder support material, and (iii) carbon nanotubes anchored directly to the surface of the metal powder support material and anchored directly to the nanoparticles on the surface of the metal powder support material; and
(b) consolidating the mixture to form the nano-structure composite material wherein the at least one powder and the metal powder support material forms the binder material and the carbon nanotubes form the fiber material of the nano-structure composite material.
2. The method of claim 1 wherein the carbon nanotubes comprise between about 0.5 wt. % and about 5 wt. % of the mixture of step (a).
3. The method of claim 1 wherein the carbon nanotubes comprise between about 0.5 wt. % and about 50 wt. % of the mixture of step (a).
4. The method of claim 1 wherein the at least one powder comprises Ni powder and NiAl powder, and the anchored nano-structured materials comprise (i) NiAl powder support material, (ii) nanoparticles formed on a surface of the NiAl powder support material, and (iii) carbon nanotubes anchored directly to the surface of the NiAl powder support material and directly to the nanoparticles on the surface of the NiAl powder support material.
5. The method of claim 1 wherein:
the at least one powder comprises Ni powder and NiAl powder, and the anchored nano-structured materials comprise (i) NiAl powder support material, (ii) nanoparticles formed on a surface of the NiAl support material, and (iii) carbon nanotubes anchored directly to the surface of the NiAl powder support material and directly to the nanoparticles on the surface of the NiAl powder support material; and
the quantity of Ni powder and the quantity of NiAl powder and the quantity of anchored nano-structured materials are in approximately a stoichiometric ratio that is selected to predominantly yield Ni 3 Al as the binder material after sintering.
6. The method of claim 1 further comprising mixing a powder comprising tungsten carbide with the mixture of step (a) to form a combined mixture, and sintering the combined mixture per step (b).
7. The method of claim 1 further comprising mixing a powder comprising tungsten carbide with the mixture of step (a) to form a combined mixture, and sintering the combined mixture per step (b), wherein the tungsten carbide comprises between about 40 vol. % and about 60 vol. % of the combined volume of tungsten carbide and the mixture of step (a).
8. The method of claim 1 further comprising mixing a powder comprising boron carbide with the mixture of step (a) to form a combined mixture, and sintering the combined mixture per step (b).
9. The method of claim 1 further comprising mixing a powder comprising boron carbide with the mixture of step (a) to form a combined mixture, and sintering the combined mixture per step (b), wherein the boron carbide comprises between about 40 vol. % and about 60 vol. % of the combined volume of boron carbide and the mixture of step (a).
10. The method of claim 1 further comprising mixing a powder comprising diamond particles with the mixture of step (a) to form a combined mixture, and sintering the combined mixture per step (b).
11. The method of claim 1 wherein for each of the carbon nanotubes an inside wall of the carbon nanotube is anchored to one of the nanoparticles.
12. The method of claim 1 wherein the anchored nano-structured materials comprise between about 5 wt. % and about 50 wt. % of the mixture.
13. The method of claim 1 wherein the anchored nano-structured materials comprise about 10 wt. % of the mixture.
14. The method of claim 1 wherein the carbon nanotubes extend from the surface of the metal powder support material and around the nanoparticles whereby the carbon nanotubes are anchored directly to both the nanoparticle and to the metal powder support material.
15. The method of claim 1 wherein the metal powder support material is selected from a group consisting of Sc, Ni, Fe, Cr, Co, Ti, V, Mn, Cu, and Zn containing metals, alloys, and intermetallics.
16. The method of claim 1 wherein the metal powder support material is selected from a group consisting of Sc, Ni, Fe, Cr, Co, Ti, V, Mn, Cu, Zn, Y, Zr, Nb, Ru, Rh, Pd, Hf, Ta, W, Re, Ir, Pt, Au, Ce, Th, and U containing metals, alloys, and intermetallics.
17. The method of claim 1 further comprising contacting the metal powder support material with a solution including metal ions from a metal salt to form nanocatalysts, heating the nanocatalysts, and exposing the nanocatalysts to a flow of organic vapor to form the anchored nano-structured materials prior to forming the mixture.
18. The method of claim 1 further comprising contacting the metal powder support material with a solution including metal ions from a metal salt to form nanocatalysts and heating the nanocatalysts under vacuum to form the anchored nano-structured materials prior to forming the mixture.