Metal alloys for the reflective or the semi-reflective layer of an optical storage medium
View Patent ↗A silver-based alloy thin film is provided for the semi-reflective coating layer of optical discs. Alloy additions to silver include copper and a rare earth metal. These alloys have moderate to high reflectivity and reasonable corrosion resistance in the ambient environment.
1. An optical storage medium, comprising:
a first layer having a pattern of features in at least one major surface;
a reflective layer;
a second layer having a pattern of features in at least one major surface; and
a semi-reflective layer including a metal alloy, said metal alloy including silver, copper, and an element R from the group consisting of terbium, thallium, thulium, ytterbium, gadolinium, and holmium;
wherein the relationship between the amounts of silver, copper, and the element R is defined by Ag x Cu y R z ; and
wherein x is between about 0.85 and about 0.9998, y is between about 0.0001 and about 0.10, and z is between about 0.0001 and about 0.05.
2. The medium of claim 1 , wherein the rare earth metal is terbium.
3. The medium of claim 1 , wherein the rare earth metal is thallium.
4. The medium of claim 1 , wherein the rare earth metal is thulium.
5. The medium of claim 1 , wherein the rare earth metal is ytterbium.
6. The medium of claim 1 , wherein the rare earth metal is gadolinium.
7. The medium of claim 1 , wherein the rare earth metal is holmium.
8. Apparatus for making an optical storage medium, the apparatus comprising, in combination:
a first layer having a pattern of features in at least one major surface;
means for sputtering a reflective layer onto the first layer;
a second layer having a pattern of features in at least one major surface;
a target comprising a metal alloy; and
means for sputtering a semi-reflective layer from the target onto the second layer;
wherein the metal alloy comprises silver, copper, and an element R from the group consisting of terbium, thallium, thulium, ytterbium, gadolinium, and holmium;
wherein the relationship between the amounts of silver, copper, and the element R is defined by Ag x Cu y R z ; and
wherein x is between about 0.85 and about 0.9998, y is between about 0.0001 and about 0.10, and z is between about 0.0001 and about 0.05.
9. The apparatus of claim 8 , wherein the rare earth metal is terbium.
10. The apparatus of claim 8 , wherein the rare earth metal is thallium.
11. The apparatus of claim 8 , wherein the rare earth metal is thulium.
12. The apparatus of claim 8 , wherein the rare earth metal is ytterbium.
13. The apparatus of claim 8 , wherein the rare earth metal is gadolinium.
14. The apparatus of claim 8 , wherein the rare earth metal is holmium.