Oil-field viscosity breaker method utilizing a peracid
View Patent ↗Aqueous well treatment fluid compositions are disclosed comprising an aqueous fluid containing polymer or copolymer for modifying fluid viscosity of the aqueous fluid and, in addition, an agent for effecting a controlled reduction in the aqueous fluid viscosity in a subterranean environment. The viscosity-reducing agent comprises a dilute concentration of peracetic acid. A method of using such compositions in oil- and gas-field treatment operations is also disclosed.
1. A method of providing controlled viscosity-reducing activity in a well treatment fluid comprising
introducing, into an aqueous well treatment fluid composition comprising a polymer or copolymer for increasing fluid viscosity or otherwise modifying fluid viscosity of the aqueous fluid composition, an agent for effecting a controlled reduction in the aqueous fluid viscosity in a subterranean environment; the viscosity-reducing agent comprising a peracetic acid in an amount of about 50 ppm to about 200 ppm wherein such amount is sufficient to provide viscosity reduction of the aqueous well treatment fluid composition in the subterranean environment to less than about 100 cP;
adjusting the pH of the aqueous fluid composition, as necessary, to a pH value in the range of 7 to 10; and
directing the aqueous well treatment fluid composition into a subterranean environment for which treatment is desired, the ground temperature of the subterranean environment being at least about 30° C.
2. The method of claim 1 wherein the temperature of the subterranean environment has a ground temperature of up to about 90° C.
3. The method of claim 2 wherein the temperature of the subterranean environment has a ground temperature of about 50° C. to about 80° C.
4. The method of claim 2 wherein the peracetic acid concentration and pH value are selected to provide substantial viscosity reduction after about 24 hours of the fluid's introduction to the subterranean environment but with such substantial viscosity reduction being delayed for at least about 3 hours after the initial directing of the fluid into the subterranean environment.
5. The method of claim 1 wherein the aqueous well treatment fluid composition further comprises a potassium salt, in an amount of about 0.5 wt % to about 5 wt %.
6. The method of claim 1 wherein the polymer or copolymer in the aqueous well treatment fluid composition is selected from the group consisting of acrylamide-derived polymers and copolymers; acrylate-derived polymers and copolymers; natural and synthetic polysaccharides and their derivatives; natural and synthetic cellulosic polymers and copolymers and their derivatives; ethylene oxide-derived polymers; and at least partially cross-linked derivatives of these polymers and copolymers.
7. The method of claim 1 wherein the polymer or copolymer in the aqueous well treatment fluid composition is present in an amount of about 0.01 wt % about 10 wt %, based on the weight of the aqueous fluid composition.
8. The method of claim 1 wherein the peracetic acid is introduced in an amount sufficient to provide viscosity reduction of the aqueous well treatment fluid composition in the subterranean environment to less than about 30 cP.