Impact modified styrenic polymers with improved stress crack properties
View Patent ↗A method of improving the stress crack resistance of an impact modified styrenic polymer comprising (a) combining about 95 to about 99.5 wt. % of an impact modified styrenic polymer with about 0.5 to about 5 wt. % of a polymer solution comprising about 25 to about 75 wt. % polyisobutylene and about 25 to about 75 wt. % of a polyolefin comprising one or more C 2 to C 12 alpha olefins.
1. A method of improving the stress crack resistance of an impact modified styrenic polymer comprising,
forming an impact modified styrenic polymer composition by,
combining about 95 to about 99.5 wt. %, based on weight of said impact modified styrenic polymer composition, of an impact modified styrenic polymer with,
about 0.5 to about 5 wt. %, based on weight of said impact modified styrenic polymer composition, of a polymer solution comprising,
about 25 to about 75 wt. %, based on weight of said polymer solution, polyisobutylene, and
about 25 to about 75 wt. %, based on weight of said polymer solution, of a polyolefin homopolymer selected from polyethylene homopolymer, low density polyethylene homopolymer, substantially linear polyethylene homopolymer, and high density polyethylene homopolymer.
2. The method according to claim 1 , wherein the styrenic polymer contains monomer residues from styrenic monomers selected from the group consisting of styrene, p-methyl styrene, tertiary butyl styrene, dimethyl styrene, nuclear brominated or chlorinated derivatives thereof and combinations thereof.
3. The method according to claim 1 , wherein the impact modified styrenic polymer contains an impact modifying polymer comprising monomer residues from styrene, butadiene, isoprene, acrylonitrile, ethylene, C 3 to C 12 alpha olefins, and combinations thereof.
4. The method according to claim 1 , wherein the polyisobutylene has a number average molecular weight ranging from about 900 to about 2500.
5. The method according to claim 1 , wherein the impact modified styrenic polymer is combined with the polymer solution by melt blending.
6. The method according to claim 1 , wherein the difference between the solubility parameter of the polyisobutylene and the solubility parameter of the polyolefin homopolymer is not more than 1 (cal/cm 3 ) 1/2 .
7. The method according to claim 1 , wherein the difference between the solubility parameters of the components of the polymer solution and the solubility parameter of the styrenic polymer is not more than 1.5 (cal/cm 3 ) 1/2 .
8. The method according to claim 1 , wherein the difference between the solubility parameters of the components of the polymer solution and the solubility parameter of the impact modifying polymer is not more than 1 (cal/cm 3 ) 1/2 .
9. An impact modified styrenic polymer composition prepared according to the method of claim 1 .
10. The impact modified styrenic polymer composition according to claim 9 , wherein the styrenic polymer contains monomer residues from styrenic monomers selected from the group consisting of styrene, p-methyl styrene, tertiary butyl styrene, dimethyl styrene, nuclear brominated or chlorinated derivatives thereof and combinations thereof.
11. The impact modified styrenic polymer composition according to claim 9 , wherein the impact modified styrenic polymer contains an impact modifying polymer comprising monomer residues from styrene, butadiene, isoprene, acrylonitrile, ethylene, C 3 to C 12 alpha olefins, and combinations thereof.
12. The impact modified styrenic polymer according to claim 9 , wherein the polyisobutylene has a number average molecular weight ranging from about 900 to about 2500.
13. The impact modified styrenic polymer composition according to claim 9 , wherein the difference between the solubility parameter of the polyisobutylene and the solubility parameter of the polyolefin homopolymer is not more than 0.5 (cal/cm 3 ) 1/2 .
14. The impact modified styrenic polymer composition according to claim 9 , wherein the difference between the solubility parameters of the components of the polymer solution and the solubility parameter of the styrenic polymer is not more than 1.5 (cal/cm 3 ) 1/2 .
15. The impact modified styrenic polymer composition according to claim 9 , wherein the difference between the solubility parameters of the components of the polymer solution and the solubility parameter of the impact modifying polymer is not more than 1 (cal/cm 3 ) 1/2 .
16. An impact modified styrenic polymer composition comprising:
(a) about 95 to about 99.5 wt. %, based on weight of said impact modified styrenic polymer composition, of an impact modified styrenic polymer comprising a styrenic polymer and an impact modifying polymer; and
(b) about 0.5 to about 5 wt. %, based on weight of said impact modified styrenic polymer composition, of a polymer solution comprising,
about 25 to about 75 wt. %, based on weight of said polymer solution, polyisobutylene, and
about 25 to about 75 wt.%, based on weight of said polymer solution, of a polyolefin homopolymer selected from polyethylene homopolymer, low density polyethylene homopolymer, substantially linear polyethylene homopolymer, and high density polyethylene homopolymer;
wherein the difference between the solubility parameter of the polyisobutylene and the solubility parameter of the polyolefin homopolymer is not more than 0.5 (cal/cm 3 ) 1/2 , the difference between the solubility parameters of the polymer solution components and the solubility parameter of the styrenic polymer is not more than 1.5 (cal/cm 3 ) 1/2 , and the difference between the solubility parameters of the polymer solution components and the solubility parameter of the impact modifying polymer is not more than 1 (cal/cm 3 ) 1/2 .
17. The impact modified styrenic polymer composition according to claim 16 , wherein the styrenic polymer contains monomer residues from styrenic monomers selected from the group consisting of styrene, p-methyl styrene, tertiary butyl styrene, dimethyl styrene, nuclear brominated or chlorinated derivatives thereof and combinations thereof.
18. The impact modified styrenic polymer composition according to claim 16 , wherein said impact modifying polymer comprises monomer residues from styrene, butadiene, isoprene, acrylonitrile, ethylene, C 3 to C 12 alpha olefins, and combinations thereof.
19. The impact modified styrenic polymer composition according to claim 16 , wherein the polyisobutylene has a number average molecular weight ranging from about 900 to about 2500.
20. The impact modified styrenic polymer composition according to claim 16 , wherein the impact modified styrenic polymer has an ESCR determined according to ASTM D1693 that is higher than the ESCR determined according to ASTM D1693 for an impact modified styrenic polymer of the same composition that does not contain the polymer solution.