Non-aqueous electrolyte secondary cell
View Patent ↗A non-aqueous electrolyte secondary cell can be charged at a high voltage of 4.3V or more and has excellent cycle characteristics and excellent high-temperature storage characteristics. The cell includes positive and negative electrodes capable of inserting and extracting lithium, and a non-aqueous electrolyte. The non-aqueous electrolyte contains a non-aqueous solvent, 1,3-dioxane and a dinitrile compound additives, and an electrolyte salt. The non-aqueous solvent contains ethylene carbonate in the range of 25% to 40% by volume under the conditions of 25° C. and 1 atm.
1. A non-aqueous electrolyte secondary cell comprising:
a positive electrode having an active material capable of inserting and extracting lithium;
a negative electrode having an active material capable of inserting and extracting lithium; and
a non-aqueous electrolyte containing a non-aqueous solvent and an electrolyte salt, the non-aqueous solvent containing ethylene carbonate in the range of 25% to 40% by volume under the conditions of 25° C. and 1 atm, wherein
the non-aqueous electrolyte further comprises 1,3-dioxane and a dinitrile compound as additives;
wherein the dinitrile compound content is in the range of 0.3% to 3.0% by mass relative to the total mass of the non-aqueous electrolyte; and wherein
the 1,3-dioxane content is in the range of 0.3% to 3.0% by mass relative to the total mass of the non-aqueous electrolyte; and
the dinitrile compound is selected from the group consisting of adiponitrile, pimelonitrile and sebaconitrile.
2. The non-aqueous electrolyte secondary cell of claim 1 , wherein the non-aqueous electrolyte further contains, as an additive, vinylene carbonate in the range of 0.5% to 3.0% by mass relative to the total mass thereof.