Rechargeable battery, anode, and current collector
View Patent ↗A rechargeable battery including a cathode and an anode each capable of inserting and extracting an electrode reaction material, and including an electrolyte, in which the anode includes an anode current collector which is formed by including a current collector body. The anode current collector is provided thereon with an active anode material layer, and a plurality of conductive particles disposed on the surface of the current collector body with the surface facing the active anode material layer. The plurality of conductive particles is formed to include spherical particles and plate-like particles. Since a tridimensional structure having irregularities is formed on the surface of the current collector body with the spherical particles and plate-like particles, anchoring effects are greatly increased. As a result, the adhesion of the active anode material layer to the anode current collector is considerably improved.
1. A rechargeable battery, comprising:
a cathode capable of inserting and extracting an electrode reaction material;
an anode capable of extracting and inserting the electrode reaction material, the anode comprising an anode current collector and an active material layer on the current collector; and
an electrolyte,
wherein,
the anode current collector comprises (i) a current collector body, and (ii) a plurality of conductive particles disposed on a surface of the current collector body,
the plurality of conductive particles includes a plurality of spherical particles and a plurality of plate-like particles, and
at least some of the plate-like particles are formed bent in a section of the anode current collector, which section intersects the surface of the current collector body, such that end portions of the particles, in a direction of extension, extend away from the surface of the current collector body.
2. The rechargeable battery according to claim 1 , wherein at least some of the plurality of plate-like particles are formed by being extended in a direction along the surface of the current collector body.
3. The rechargeable battery according to claim 1 , wherein the spherical particles overlie the plate-like particles on the surface of the anode current collector body.
4. The rechargeable battery according to claim 1 , wherein some of the plurality of plate-like particles at least partially overlap with each other on the surface of the anode current collector body.
5. The rechargeable battery according to claim 1 , wherein the spherical particles and the plate-like particles are metal particles and metal oxides are on the spherical particles and the plate-like particles.
6. The rechargeable battery according to claim 5 , wherein the metal oxides are substantially fibrous in shape.
7. The rechargeable battery according to claim 1 , wherein the spherical particles and the plate-like particles are formed by a spraying method.
8. The rechargeable battery according to claim 1 , wherein each of the current collector body and the conductive particles include copper (Cu).
9. The rechargeable battery according to claim 1 , wherein the active anode material layer includes silicon (Si).
10. The rechargeable battery according to claim 1 , wherein the active anode material layer is formed by a gas phase method.
11. The rechargeable battery according to claim 1 , wherein the electrode reaction material is a lithium ion.
12. An anode, comprising:
an anode current collector including a current collector body; and
an active anode material layer on the anode current collector,
wherein,
a plurality of conductive particles are on a surface of the current collector body,
the plurality of conductive particles includes a plurality of spherical particles and a plurality of plate-like particles, and
at least some of the plate-like particles are formed bent in a section of the anode current collector, which section intersects the surface of the current collector body, such that end portions of the particles, in a direction of extension, extend away from the surface of the current collector body.
13. A current collector, comprising a current collector body;
wherein:
the current collector is provided with a plurality of conductive particles on a surface of the current collector body,
the plurality of conductive particles includes a plurality of spherical particles and a plurality of plate-like particles, and
at least some of the plate-like particles are formed bent in a section of the anode current collector, which section intersects the surface of the current collector body, such that end portions of the particles, in a direction of extension, extend away from the surface of the current collector body.