Semiconductor nanocrystal synthesis using a catalyst assisted two-phase reaction
View Patent ↗A method for producing a high yield of high quality, low size distribution, and size tunable semiconductor nanocrystals. The method produces III-V, II-VI, II-V, IV-VI, IV, ternary, quarternary, and quinary semiconductor nanocrystals (quantum dots) using a catalyst assisted two-phase reaction.
1. A method of synthesizing semiconductor nanocrystals comprising:
reacting a metal chalcogenide with an organic acid to form a metal-acid complex precursor and water; wherein the metal chalcogenide is not completely dissolved in the organic acid,
adding to the metal-acid complex precursor and water a solution containing Se:TBP (selenium dissolved in tributylphosphine), Se:TOPO (selenium dissolved in trioctylphosphine oxide), or both, to form nanocrystal seeds and an acidic ion; and growing a plurality of semiconductor nanocrystals from the nanocrystal seeds, wherein the acidic ion combines with a catalyst to reform the organic acid.
2. The method of claim 1 , wherein the catalyst includes water.
3. The method of claim 1 , wherein the organic acid includes at least one acid selected from a group consisting of: oleic acid, TDPA (Thiodipropionic Acid), HPA (Hydroxypropyl Acrylate), and stearic acid.
4. The method of claim 1 , further comprising:
removing a sample of the semiconductor nanocrystals; and
determining a size of at least one semiconductor nanocrystal in the sample of semiconductor nanocrystals.
5. The method of claim 4 , further comprising:
purifying the sample of the semiconductor nanocrystals.
6. The method of claim 4 , further comprising:
removing an additional sample of the semiconductor nanocrystals; and
determining a size of at least one additional semiconductor nanocrystal in the additional sample of semiconductor nanocrystals.
7. The method of claim 5 , wherein the size of the at least one additional semiconductor nanocrystal is greater than the size of the at least one semiconductor nanocrystal.
8. The method of claim 6 , further comprising:
purifying the additional sample of the semiconductor nanocrystals.
9. The method of claim 1 , wherein a concentration of the metal-acid complex precursor remains substantially constant during the growing the plurality of semiconductor nanocrystals.
10. The method of claim 1 , wherein the plurality of semiconductor nanocrystals is selected from a group consisting of: III-V semiconductor nanocrystals, II-VI semiconductor nanocrystals, II-V semiconductor nanocrystals, IV-VI semiconductor nanocrystals, and IV semiconductor nanocrystals.
11. The method of claim 10 , wherein the plurality of semiconductor nanocrystals is selected from a group consisting of: ternary semiconductor nanocrystals, quarternary semiconductor nanocrystals, and quinary semiconductor nanocrystals.
12. The method of claim 1 , wherein the plurality of semiconductor nanocrystals have a low size distribution.
13. The method of claim 12 , further comprising:
purifying the plurality of semiconductor nanocrystals.