Resin substrate provided with coating layer
View Patent ↗To provide a resin substrate provided with a coating layer having excellent weather resistance and thereby capable of maintaining properties of the resin such as transparency and fracture resistance over a long period of time. A resin substrate provided with a coating layer, which comprises a substrate made of a resin containing an aromatic ring and a coating layer containing an acrylic polymer having an acid value of at most 1 mg KOH/g, a glass transition point of from 60° C. to 150° C. and a mass average molecular weight of from 90,000 to 1,000,000, and an ultraviolet light absorbing component selected from a polymer having ultraviolet light absorbing groups and an ultraviolet light absorber, having an average of absorption coefficients of from 3.5 g/(mg·cm) to 100 g/(mg·cm) to light in a wavelength region of from 350 nm to 380 nm, formed on at least one surface of the substrate.
1. A resin substrate provided with a coating layer, which comprises:
a substrate made of a resin containing an aromatic ring, and
a coating layer formed on at least one surface of the substrate, said coating layer having a thickness of from 0.5 μm to 10 μm and comprising:
(1) an acrylic polymer comprising at least one member selected from the group consisting of an alkyl acrylate and an alkyl methacrylate, as main monomer units, and
(2) an ultraviolet light absorbing component,
wherein the acrylic polymer (1) has an acid value of at most 1 mg KOH/g, a glass transition point of from 60° C. to 150° C., and a mass average molecular weight of from 90,000 to 1,000,000, and
wherein the average of absorption coefficients of the ultraviolet light absorbing component (2) to light in a wavelength region of from 350 nm to 380 nm is from 3.5 g/(mg·cm) to 100 g/(mg·cm), and said ultraviolet light absorbing component (2) is 2-[4-(4,6-bis-{2-hydroxy-4-[1-(6-methyl-heptyloxycarbonyl)-ethoxy]-phenyl}-[1,3,5]triazin-2-yl)-3-hydroxy-phenoxy]-propionic acid 6-methyl-heptyl ester.
2. The resin substrate provided with a coating layer according to claim 1 , wherein the acrylic polymer (1) is a homopolymer or a copolymer comprising an alkyl methacrylate having an alkyl group having at most 6 carbon atoms as the main monomer units.
3. The resin substrate provided with a coating layer according to claim 1 , wherein the content of the ultraviolet light absorbing component (2) is from 1 mass % to 30 mass % to the total amount of components constituting the coating layer.
4. The resin substrate provided with a coating layer according to claim 1 , wherein the total content of the acrylic polymer (1) and the polymer chain moiety of the ultraviolet light absorbing component (2), excluding ultraviolet light absorbing groups, is from 50 to 97 mass % to the total amount of components constituting the coating layer.
5. The resin substrate provided with a coating layer according to claim 1 , wherein the content of the ultraviolet light absorbing component (2) is from 9.1 mass % to 30 mass % to the total amount of components constituting the coating layer.