Heat-peelable pressure-sensitive adhesive sheet for cutting laminated ceramic sheet and method for cut-processing laminated ceramic sheet
The invention relates to a heat-peelable pressure-sensitive adhesive sheet for cutting a laminated ceramic sheet, which is used for temporary fixing at cutting of the laminated ceramic sheet, the heat-peelable pressure-sensitive adhesive sheet including a base material and, formed on at least one surface of the base material, a heat-expandable pressure-sensitive adhesive layer containing a pressure-sensitive adhesive and a foaming agent, in which the heat-expandable pressure-sensitive adhesive layer has a gel fraction of 50% by weight or more, and the heat-expandable pressure-sensitive adhesive layer has a glass transition temperature of −40° C. to 30° C.
1. A heat-peelable pressure-sensitive adhesive sheet for cutting a laminated ceramic sheet, which is used for temporary fixing at cutting of the laminated ceramic sheet,
the heat-peelable pressure-sensitive adhesive sheet comprising a base material and, formed on at least one surface of the base material, a heat-expandable pressure-sensitive adhesive layer containing a pressure-sensitive adhesive for imparting pressure-sensitive adhesiveness and a heat-expandability imparting foaming agent,
wherein the heat-expandable pressure-sensitive adhesive layer has a gel fraction of 50% by weight or more, and
wherein the heat-expandable pressure-sensitive adhesive layer has a glass transition temperature of −40° C. to 30° C.
2. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein a base polymer of the pressure-sensitive adhesive forming the heat-expandable pressure-sensitive adhesive layer is an acrylic polymer.
3. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the pressure-sensitive adhesive forming the heat-expandable pressure-sensitive adhesive layer further contains a crosslinking agent.
4. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the heat-expandable pressure-sensitive adhesive layer has an adhesive force at 23° C. at a peeling angle of 180° and a drawing rate at 300 mm/min of 2 N/20 mm width to 20 N/20 mm width when the heat-expandable pressure-sensitive adhesive layer is allowed to stand under an atmosphere of 23° C. for 30 minutes after attached to a polyethylene terephthalate film having a thickness of 25 μm at 23° C., and
wherein the heat-expandable pressure-sensitive adhesive layer has an adhesive force at 80° C. at a peeling angle of 180° and a drawing rate at 300 mm/min of 1 N/20 mm width to 15 N/20 mm width when the heat-expandable pressure-sensitive adhesive layer is allowed to stand under an atmosphere of 80° C. for 30 minutes after attached to a polyethylene terephthalate film having a thickness of 25 μm at 23° C.
5. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the foaming agent is a heat-expandable microsphere.
6. The heat-peelable pressure-sensitive adhesive sheet according to claim 5 , wherein the heat-expandable microsphere is a microsphere in which a substance easily gasified and expanded is included in a shell having elasticity.
7. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the foaming agent is an inorganic foaming agent.
8. The heat-peelable pressure-sensitive adhesive sheet according to claim 7 , wherein the inorganic foaming agent is an ammonium carbonate, an ammonium hydrogen carbonate, a sodium hydrogen carbonate, an ammonium nitrate, a sodium borohydride, or an azide.
9. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the foaming agent is an organic foaming agent.
10. The heat-peelable pressure-sensitive adhesive sheet according to claim 9 , wherein the organic foaming agent is water, a chlorofluoroalkane-based compound, an azo-based compound, a hydrazine-based compound, a semicarbazide-based compound, a triazole-based compound, or an N-nitroso-based compound.
11. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the foaming agent is contained in an amount of 1 part by weight to 150 parts by weight based on 100 parts by weight of the base polymer.
12. The heat-peelable pressure-sensitive adhesive sheet according to claim 5 , wherein the heat-expandable microsphere has an average particle diameter of 100 μm or less.
13. The heat-peelable pressure-sensitive adhesive sheet according to claim 1 , wherein the glass transition temperature of the heat-expandable pressure-sensitive adhesive layer is −30° C. to 25° C.
14. The heat-peelable pressure-sensitive adhesive sheet according to claim 13 , wherein the glass transition temperature of the heat-expandable pressure-sensitive adhesive layer is −30° C. to 20° C.
15. The heat-peelable pressure-sensitive adhesive sheet according to claim 14 , wherein the glass transition temperature of the heat-expandable pressure-sensitive adhesive layer is −15° C. to 15° C.