Gallium-doped phosphocalcic compounds

1. A process in solution for the manufacture of a gallium-doped phosphocalcic compound of formula (I): Ca (10.5-1.5x) Ga x (PO 4 ) 7 having a structure close to β-tricalcium phosphate (β-TCP), wherein 0<x<1 and the salts, hydrates and mixtures thereof, comprising the following steps:

(a) preparing an aqueous solution containing a calcium compounds and an appropriate quantity of a gallium compound;

(b) adjusting the pH of the solution obtained in step (a) to a value of 8.5 to 12;

(c) adding to said solution an appropriate quantity of a phosphate compound;

(d) precipitating the gallium doped phosphocalcic compound by adjusting the pH of the obtained solution to a value of 7.0 to 12;

(e) separating the precipitated gallium doped phosphocalcic compound from the solution; and

(f) calcining the gallium doped phosphocalcic compound obtained.

2. The process in solution according to claim 1 , wherein said gallium salt in step (a) is selected from the group consisting of gallium acetate, gallium carbonate, gallium citrate, gallium chloride, gallium fluoride, gallium formate, gallium nitrate, gallium oxalate, gallium sulfate, gallium hydroxide, and gallium oxide hydroxide.

3. The process in solution according to claim 1 , wherein said calcium solid precursor in step (a) is selected from the group consisting of calcium nitrate tetrahydrate, calcium acetate, calcium chloride and calcium fluoride.

4. The process in solution according to claim 1 , wherein the phosphate compound is ammonium hydrogen phosphate.

5. The process in solution according to claim 1 , wherein step (d) is carried out at a temperature between 37 and 80° C.