IP Library Granted Patent US 7,939,488
Granted Patent B2
US 7,939,488 · App. 12/717,706 · Granted May 10, 2011

Natural disinfecting cleaners

Assignee: The Clorox Company
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Quick Facts
Patent No.
US 7,939,488
App. No.
12/717,706
Granted
May 10, 2011
Kind
B2
Abstract

A cleaning composition with a limited number of natural ingredients contain a hydrophobic syndetic, a hydrophilic syndetic, and a biguanide or a cationic quaternary ammonium salt. The cleaning composition can be used to clean laundry, soft surfaces, and hard surfaces and cleans as well or better than commercial compositions containing synthetically derived cleaning agents.

Claims (75)

1. A natural composition consisting essentially of:

a. a hydrophilic syndetic selected from the group consisting of C 6 alkyl polyglucoside, C 6 to C 8 alkyl polyglucoside, C 8 alkyl polyglucoside, a C 4 to C 8 alkyl polypentoside and combinations thereof;

b. a hydrophobic syndetic selected from the group consisting of amine oxide, a fatty acid, a fatty alcohol, a sterol, a sorbitan fatty acid ester, a glycerol fatty acid ester, a polyglycerol fatty acid ester, a C 14 to C 22 alkyl polypentoside, and combinations thereof;

c. a biguanide compound or a cationic quaternary ammonium salt, or mixtures thereof;

d. a nonionic surfactant selected from a C 8 to C 10 alkyl polypentoside;

e. optionally an organic chelating agent from the group consisting of 2-hydroxyacids, 2-hydroxyacid derivatives, glutamic acid, glutamic acid derivatives, gluconate, and mixtures thereof;

f. optionally a solvent selected from the group consisting of propylene glycol, 1,3-propanediol, ethanol, sorbitol, glycerol and combinations thereof;

g. optionally an anionic surfactant selected from the group consisting of sodium lauryl sulfate, sodium alkyl α-sulfomethyl ester, and combinations thereof;

h. optional ingredients selected from pH adjusting agents, builders, calcium salts, boric acid or borate, enzymes, dyes, colorants, fragrances, preservatives, fluorescent whitening agents, bluing agents, defoamers, bleaches, thickeners, amino acids, monoethanolamine, alkyl pyrrolidone, C 10 to C 12 alkyl polypentoside, anti-redeposition polymers, salts of EDTA, DTPA, GLDA, EDDS, TMG, Tiron and combinations thereof.

2. The composition of claim 1 , wherein the composition does not contain alkyl glycol ethers, alcohol alkoxylates, alkyl monoglycerolether sulfate, alkyl ether sulfates, alkanolamines, alkyl ethoxysulfates, phosphates, linear alkylbenzene sulfonate (“LAS”), linear alkylbenzene sulphonic acid (“HLAS”) or nonylphenol ethoxylate (“NPE”), or soluble metal ions selected from the group of silver, copper, or zinc.

3. The composition of claim 1 , wherein the composition does not contain a solvent selected from the group consisting of propylene glycol, 1,3-propanediol, ethanol, sorbitol, glycerol, n-propanol, isopropanol, butanol, pentanol, hexanol, methylene glycol, ethylene glycol, butylene glycol, D-xylitol, D-arabitol, benzyl alcohol, phenoxyethanol, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monohexyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monohexyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol n-propyl ether, propylene glycol monobutyl ether, propylene glycol t-butyl ether, di- or tri-polypropylene glycol methyl or ethyl or propyl or butyl ether, acetate and propionate esters of glycol ethers and combinations thereof.

4. The composition of claim 1 , wherein the composition requires an organic chelating agent selected from the group consisting of 2-hydroxyacids, 2-hydroxyacid derivatives, glutamic acid, glutamic acid derivatives, gluconate, and mixtures thereof.

5. The composition of claim 1 , wherein the composition is a natural composition, wherein said natural composition has

a) at least 95% of the components of the natural composition are derived from plant and mineral based materials;

b) the natural composition is biodegradable;

c) the natural composition is minimally toxic to humans;

d) the natural composition has a LD50>5000 mg/kg; and

e) the natural composition does not contain non-plant based ethoxylated surfactants, linear alkylbenzene sulfonates, ether sulfates surfactants or nonylphenol ethoxylate.

6. The composition of claim 5 , the composition is an ecofriendly composition, wherein said ecofriendly composition has

a) at least 99% of the components of the ecofriendly composition are derived from plant and mineral based materials;

b) the ecofriendly composition is biodegradable;

c) the ecofriendly composition is minimally toxic to humans;

d) the ecofriendly composition has a LD50>5000 mg/kg; and

e) the ecofriendly composition does not contain non-plant based ethoxylated surfactants, linear alkylbenzene sulfonates, ether sulfate surfactants or nonylphenol ethoxylate.

7. A natural composition consisting essentially of:

a. a hydrophilic syndetic selected from C 4 to C 8 alkyl polypentoside;

b. a hydrophobic syndetic selected from the group consisting of an amine oxide, a fatty acid, a fatty alcohol, a sterol, a sorbitan fatty acid ester, a glycerol fatty acid ester, a polyglycerol fatty acid ester, a C 14 to C 22 alkyl polypentoside, and combinations thereof;

c. a biguanide compound or a cationic quaternary ammonium salt, or mixtures thereof;

d. optionally, an organic chelating agent from the group consisting of 2-hydroxyacids, 2-hydroxyacid derivatives, glutamic acid, glutamic acid derivatives, gluconate and mixtures thereof;

e. optionally a solvent selected from the group consisting of propylene glycol, 1,3-propanediol, ethanol, sorbitol, glycerol and combinations thereof;

f. optionally a nonionic surfactant selected from the group consisting of an alkylpolyglucoside having chain lengths from C 10 to C 20 , alkyldiethanolamide, alkylethanolamide, an alkyl (poly glycerol ether), a C 8 to C 14 alkyl polypentoside, an alkyl pyrrolidone having chain lengths C 8 and greater, and combinations thereof;

g. optionally, an anionic surfactant selected from the group consisting of a fatty alcohol sulfate, an alkyl a-sulfomethyl ester, an alkyl sulfosuccinate, and combinations thereof;

h. optionally an amphoteric surfactant selected from the group consisting of sarcosinate, tauride, betaine, sulfobetaine and combinations thereof; and

i. optional ingredients selected from pH adjusting agents, calcium salts, boric acid, enzymes, dyes, colorants, fragrances, preservatives, fluorescent whitening agents, bluing agents, defoamers, bleaches, thickeners, amino acids, monoethanolamine, anti-redeposition polymers, salts of EDTA, DTPA, GLDA, EDDS, TMG, Tiron and combinations thereof.

8. The composition of claim 7 , wherein the composition requires a nonionic surfactant selected from the group consisting of an alkylpolyglucoside having chain lengths from C 10 to C 20 , alkyldiethanolamide, alkylethanolamide, an alkyl (poly glycerol ether), a C 8 to C 14 alkyl polypentoside, an alkyl pyrrolidone having chain lengths C 8 and greater, and combinations thereof.

9. The composition of claim 7 , wherein the composition does not contain alkyl glycol ethers, alcohol alkoxylates, alkyl monoglycerolether sulfate, alkyl ether sulfates, alkyl ethoxysulfates, phosphates, linear alkylbenzene sulfonate (“LAS”), linear alkylbenzene sulphonic acid (“HLAS”) or nonylphenol ethoxylate (“NPE”) or soluble metal ions selected from the group of silver, copper, or zinc.

10. The composition of claim 7 , wherein the composition is a natural composition, wherein said natural composition has

a) at least 95% of the components of the natural composition are derived from plant and mineral based materials;

b) the natural composition is biodegradable;

c) the natural composition is minimally toxic to humans;

d) the natural composition has a LD50>5000 mg/kg; and

e) the natural composition does not contain non-plant based ethoxylated surfactants, linear alkylbenzene sulfonates, ether sulfates surfactants or nonylphenol ethoxylate.

11. The composition of claim 10 , the composition is an ecofriendly composition, wherein said ecofriendly composition has

a) at least 99% of the components of the ecofriendly composition are derived from plant and mineral based materials;

b) the ecofriendly composition is biodegradable;

c) the ecofriendly composition is minimally toxic to humans;

d) the ecofriendly composition has a LD50>5000 mg/kg; and

e) the ecofriendly composition does not contain non-plant based ethoxylated surfactants, linear alkylbenzene sulfonates, ether sulfates surfactants or nonylphenol ethoxylate.

12. The composition of claim 7 , wherein the composition does not contain a solvent selected from the group consisting of propylene glycol, 1,3-propanediol, ethanol, sorbitol, glycerol, n-propanol, isopropanol, butanol, pentanol, hexanol, methylene glycol, ethylene glycol, butylene glycol, D-xylitol, D-arabitol, benzyl alcohol, phenoxyethanol, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monohexyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monohexyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol n-propyl ether, propylene glycol monobutyl ether, propylene glycol t-butyl ether, di- or tri-polypropylene glycol methyl or ethyl or propyl or butyl ether, acetate and propionate esters of glycol ethers and combinations thereof.

13. The composition of claim 7 , wherein the hydrophobic syndetic is a fatty acid and the fatty acid is a coconut fatty acid.

14. A natural composition comprising:

a. a hydrophilic syndetic selected from C 4 to C 8 alkyl polypentoside;

b. a hydrophobic syndetic selected from the group consisting of an amine oxide, a fatty acid, a fatty alcohol, a sterol, a sorbitan fatty acid ester, a glycerol fatty acid ester, a polyglycerol fatty acid ester, a C 14 to C 22 alkyl polypentoside, and combinations thereof;

c. a biguanide compound or a cationic quaternary ammonium salt, or mixtures thereof;

d. optionally a solvent selected from the group consisting of 1,3-propanediol, sorbitol, glycerol and combinations thereof;

e. optionally a nonionic surfactant selected from the group consisting of an alkylpolyglucoside having chain lengths from C 8 to C 20 , alkyldiethanolamide, alkylethanolamide, an alkyl (poly glycerol ether), a C 8 to C 14 alkyl polypentoside, an alkyl pyrrolidone having chain lengths C 8 and greater, and combinations thereof;

f. optionally an amphoteric surfactant selected from the group consisting of sarcosinate, tauride, betaine, sulfobetaine and combinations thereof;

g. optionally, an anionic surfactant selected from the group consisting of a fatty alcohol sulfate, an alkyl a-sulfomethyl ester, an alkyl sulfosuccinate, and combinations thereof;

h. optionally an organic chelating agent from the group consisting of 2-hydroxyacids, 2-hydroxyacid derivatives, glutamic acid, glutamic acid derivatives, gluconate, and mixtures thereof; and

i. optional ingredients selected from pH adjusting agents, calcium salts, boric acid, enzymes, dyes, colorants, fragrances, preservatives, fluorescent whitening agents, bluing agents, defoamers, bleaches, thickeners, amino acids, monoethanolamine, anti-redeposition polymers, ethanol, propylene glycol, salts of EDTA, DTPA, GLDA, EDDS, TMG, Tiron, and combinations thereof,

wherein the composition does not contain alkyl glycol ethers, alcohol alkoxylates, alkyl monoglycerolether sulfate, alkyl ether sulfates, alkyl ethoxysulfates, phosphates, linear alkylbenzene sulfonate (“LAS”), linear alkylbenzene sulphonic acid (“HLAS”) nonylphenol ethoxylate (“NPE”), soluble metal ions selected from the group of silver, copper, or zinc, triclosan, p-chlorometaxylenol or iodine, pentose alcohols and their isomers, D-xylitol and its isomers, D-arabitol and its isomers, aryl alcohols, benzyl alcohol, phenoxyethanol, or homopolymers of the monomers diallyl dimethyl ammonium chloride or ethylene imine.

15. The composition of claim 14 , wherein the composition requires a nonionic surfactant selected from the group consisting of an alkylpolyglucoside having chain lengths from C 8 to C 20 , alkyldiethanolamide, alkylethanolamide, an alkyl (poly glycerol ether), a C 8 to C 14 alkyl polypentoside, an alkyl pyrrolidone having chain lengths C 8 and greater, and combinations thereof.

16. The composition of claim 14 , wherein the composition is a natural composition, wherein said natural composition has

a) at least 95% of the components of the natural composition are derived from plant and mineral based materials;

b) the natural composition is biodegradable;

c) the natural composition is minimally toxic to humans;

d) the natural composition has a LD50>5000 mg/kg; and

e) the natural composition does not contain non-plant based ethoxylated surfactants, linear alkylbenzene sulfonates, ether sulfates surfactants or nonylphenol ethoxylate.

17. The composition of claim 16 , the composition is an ecofriendly composition, wherein said ecofriendly composition has

a) at least 99% of the components of the ecofriendly composition are derived from plant and mineral based materials;

b) the ecofriendly composition is biodegradable;

c) the ecofriendly composition is minimally toxic to humans;

d) the ecofriendly composition has a LD50>5000 mg/kg; and

e) the ecofriendly composition does not contain non-plant based ethoxylated surfactants, linear alkylbenzene sulfonates, ether sulfates surfactants or nonylphenol ethoxylate.

18. The composition of claim 14 , wherein the composition does not contain a solvent selected from the group consisting of propylene glycol, 1,3-propanediol, ethanol, sorbitol, glycerol, n-propanol, isopropanol, butanol, pentanol, hexanol, methylene glycol, ethylene glycol, butylene glycol, D-xylitol, D-arabitol, benzyl alcohol, phenoxyethanol, ethylene glycol monopropyl ether, ethylene glycol monobutyl ether, ethylene glycol monohexyl ether, diethylene glycol monopropyl ether, diethylene glycol monobutyl ether, diethylene glycol monohexyl ether, propylene glycol methyl ether, propylene glycol ethyl ether, propylene glycol n-propyl ether, propylene glycol monobutyl ether, propylene glycol t-butyl ether, di- or tri-polypropylene glycol methyl or ethyl or propyl or butyl ether, acetate and propionate esters of glycol ethers and combinations thereof.

Assignments (1)
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Mar 4, 2010
From: SCHEUING, DAVID R.; ZHANG, RUI
To: THE CLOROX COMPANY
Reel/Frame 024030/0768 →
Continuity (5)
Continuation In Part 12558795 · Sep 14, 2009
Continuation In Part 12343202 · Dec 23, 2008
Continuation In Part 12198677 · Aug 26, 2008
Continuation In Part 12198685 · Aug 26, 2008
Related Publication 20100160201A1 · Jun 24, 2010