Fabrication of catalyst coated diffusion media layers containing nanostructured thin catalytic layers
View Patent ↗A method of transferring nanostructured thin catalytic layers to a gas diffusion layer and thus making a catalyst coated diffusion media is described. The method includes treating the gas diffusion layer with a temporary adhesive to temporarily increase the adhesion strength within the microporous layer and to carbon fiber paper substrate, transferring the nanostructured thin catalytic layer to the microporous side of a gas diffusion media layer. The nanostructured thin catalytic layer can then be further processed, including adding additional components or layers to the nanostructured thin catalytic layer on the gas diffusion media layer. Preparation of catalyst coated diffusion media and a catalyst coated diffusion media based membrane electrode assembly (MEA) are also described.
1. A method of making a catalyst coated diffusion media comprising:
providing an electrode decal comprising a carrying substrate with a nanostructured thin catalytic layer thereon, the nanostructured thin catalytic layer having a first surface and a second surface, the first surface of the nanostructured thin catalytic layer adjacent the carrying substrate;
providing a porous transfer substrate with an adjacent adhesive layer;
adhering the second surface of the nanostructured thin catalytic layer adjacent to the adhesive layer to form a composite structure;
removing the carrying substrate from the composite structure such that a residual layer formed on the first surface of the nanostructured thin catalytic layer of the electrocatalyst decal becomes exposed; and
removing the adhesive layer from the composite structure and further removing the residual layer from the composite structure to form a reconstructed electrode decal comprising the porous transfer substrate and the nanostructured thin catalytic layer, wherein the second surface of the nanostructured thin catalytic layer is adjacent to the porous transfer substrate;
providing a gas diffusion media layer comprising a conductive porous substrate and a microporous layer such that the microporous layer is adjacent to the first surface of the nanostructured thin catalytic layer;
applying a bonding layer adjacent to the microporous layer, the first surface of the nanostructured thin catalytic layer, or both such that the first surface of the nanostructured thin catalytic layer is adjacently adhered to the microporous layer with the bonding layer;
removing the porous transfer substrate; and
removing at least a portion of the bonding layer;
to form the catalyst coated diffusion media comprising the conductive porous substrate, the microporous layer, and the nanostructured thin catalytic layer adjacent to the microporous layer on a side opposite the conductive porous substrate.
2. The method of claim 1 further comprising coating a solution onto the nanostructured thin catalytic layer after removing the carrying substrate and at least the portion of the bonding layer, the solution forming an additional layer on the first surface of the nanostructured thin catalytic layer.
3. The method of claim 2 wherein the solution includes at least one of an ionomer, conductive particles, carbon powder, carbon fibers, catalyst, titanium dioxide, silica, nanofibers, or nanotubes.
4. The method of claim 1 wherein applying the bonding layer comprises applying a solution comprising an adhesive, an ionomer, or both.
5. The method of claim 4 wherein the solution further comprises at least one of conductive particles, carbon powder, carbon fibers, catalyst, titanium dioxide, silica, nanofibers, or nanotubes.
6. The method of claim 4 wherein the solution further comprises a solvent which wets the microporous layer.
7. The method of claim 1 wherein the bonding layer is adjacent to the microporous layer, and wherein applying the bonding layer comprises applying a solution comprising polyvinyl alcohol, water, and an alcohol.
8. The method of claim 1 wherein the electrode decal further comprises an additional layer comprising at least one of an ionomer, conductive particles, carbon powder, carbon fibers, catalyst, titanium dioxide, silica, nanofibers, or nanotubes, wherein the additional layer is positioned between the porous transfer substrate and the nanostructured thin catalytic layer, or on the nanostructured thin catalytic layer on the side opposite the porous transfer substrate.
9. The method of claim 1 wherein the adhesive layer further comprises at least one of an ionomer, conductive particles, carbon powder, carbon fibers, catalyst, titanium dioxide, silica, nanofibers, or nanotubes.
10. The method of claim 1 wherein an additional layer is coated on the nanostructured thin catalytic layer on the reconstructed electrode decal after the carrying substrate and the adhesive are removed, wherein the additional layer comprises at least one of an ionomer, conductive particles, carbon powder, carbon fibers, catalyst, titanium dioxide, silica, nanofibers, or nanotubes.
11. The method of claim 1 wherein there is an additional layer between the porous transfer substrate and the adjacent adhesive layer, wherein the additional layer comprises at least one of an ionomer, conductive particles, carbon powder, carbon fibers, catalyst, titanium dioxide, silica, nanofibers, or nanotubes.
12. The method of claim 1 wherein the electrode decal includes at least two nanostructured thin catalytic layers.
13. The method of claim 1 wherein the nanostructured thin catalytic layer is adhered adjacent to the microporous layer using a hot press process.