Silica removal from pregnant leach solutions
View Patent ↗The present invention relates generally to a process for removing dissolved or colloidal silica from a pregnant leach solution (“PLS”). More particularly, an exemplary embodiment of the present invention relates to a process which mixes PLS with an acid source, preferably lean electrolyte, to induce formation of colloidal silica that can then be collected and removed. Additionally, in an exemplary embodiment of the present invention, at least one silica seeding agent is added to induce formation of colloidal silica, at least one flocculant is added to induce aggregation of the colloidal silica, and a solid-liquid separation process is utilized to remove advantageous amounts or substantially all of the colloidal silica, thereby providing relief from supersaturation of dissolved silica in the metal recovery processes.
1. A method for providing relief from dissolved silica in pregnant leach solutions comprising:
reacting a feed stream comprising a metal-bearing material to yield a pregnant leach solution comprising a metal-value and dissolved silica;
adding acid and at least one seeding agent to said pregnant leach solution to yield a pregnant leach solution comprising a metal-value and colloidal silica;
adding at least one flocculant to said pregnant leach solution comprising a metal-value and colloidal silica, such that said colloidal silica agglomerates;
removing at least a portion of said agglomerated silica;
recovering at least a portion of said metal-value from said pregnant leach solution.
2. The method of claim 1 , wherein said reacting step comprises pressure leaching operation.
3. The method of claim 2 , wherein said pressure leaching operation is operated at a temperature of from about 140° C. to about 250° C.
4. The method of claim 1 , wherein said removing step comprises a solid-liquid separation step.
5. The method of claim 4 , wherein said solid-liquid separation step comprises at least one of a filtration system, a counter-current decantation (CCD) circuit, a thickener, a centrifuge, a screen, a flotation method, a clarification method, and a flocculation method to remove colloidal silica.
6. The method of claim 1 , wherein said at least one seeding agent comprises any silica based seed.
7. The system of claim 6 , wherein the silica based seed is recycled from the electrowinning step.
8. The method of claim 1 , wherein said at least one seeding agent comprises at least one of a fumed silica and a polyethylene oxide (PEO)-silica agglomerates.
9. The method of claim 1 , wherein said portion of the silica removed is an advantageous amount, wherein said advantageous amount is more silica than would be removed in a solid/liquid separation step without the addition of said seeding agent and said flocculant at the same temperature, acidity, and with the same mixing and residence time.
10. The method of claim 9 , wherein said advantageous amount of removed colloidal silica is greater than about 60% of the total silica in the metal extraction process.
11. A method for providing relief from dissolved silica in pregnant leach solutions comprising:
reacting a feed stream comprising a metal-bearing material to yield a pregnant leach solution comprising dissolved silica;
adding acid and at least one seeding agent to said pregnant leach solution to yield a pregnant leach solution comprising colloidal silica;
adding at least one flocculant to said pregnant leach solution comprising colloidal silica, such that said colloidal silica agglomerates;
removing at least a portion of said agglomerated silica.
12. The method of claim 11 , wherein said reacting step comprises pressure leaching operation.
13. The method of claim 12 , wherein said pressure leaching operation is operated at a temperature of from about 140° C. to about 250° C.
14. The method of claim 11 , wherein said removing step comprises a solid-liquid separation step.
15. The method of claim 14 , wherein said solid-liquid separation step comprises at least one of a filtration system, a counter-current decantation (CCD) circuit, a thickener, a centrifuge, a screen, a flotation method, a clarification method, and a flocculation method to remove colloidal silica.
16. The method of claim 11 , wherein said seeding agent comprises any silica based seed.
17. The system of claim 16 , wherein the silica based seed is recycled from the electrowinning step.
18. The method of claim 11 , wherein said seeding agent comprises at least one of a fumed silica and a polyethylene oxide (PEO)-silica agglomerates.
19. The method of claim 11 , wherein said portion of the colloidal silica removed is an advantageous amount, wherein said advantageous amount is more silica than would be removed in a solid/liquid separation step without the addition of said seeding agent and said flocculant at the same temperature, acidity, and with the same mixing and residence time.
20. The method of claim 19 , wherein said advantageous amount of removed colloidal silica is greater than about 60% of the total silica in the metal extraction process.