Method for producing propylene oxide
View Patent ↗Disclosed is a method for producing propylene oxide wherein propylene is directly oxidized with oxygen, as required, water and a catalytic amount of hydrogen in a gas phase in the presence of a gold cluster catalyst supported on an alkali-treated titanosilicalite or mesoporous titanosilicate support, which is produced by an alkaline treatment of titanosilicalite or mesoporous titanosilicate with aqueous solution of NaOH, KOH or CsOH.
1. A method for producing propylene oxide, wherein propylene is directly oxidized with oxygen in a gas phase in the presence of a gold cluster catalyst supported on an aqueous-alkali-treated titanosilicalite support or on an aqueous-alkali-treated mesoporous titanosilicate support and wherein the gold clusters have an average particle diameter of 2 nm or less.
2. The method for producing propylene oxide according to claim 1 , wherein water is further added to a feed gas comprising propylene and oxygen.
3. The method for producing propylene oxide according to claim 1 , wherein a catalytic amount of hydrogen gas is further added to a feed gas comprising propylene and oxygen.
4. The method for producing propylene oxide according to claim 2 , wherein a catalytic amount of hydrogen gas is further added to a feed gas comprising propylene, oxygen and water.
5. The method for producing propylene oxide according to claim 1 , wherein the aqueous-alkali-treated titanosilicalite or mesoporous titanosilicate is produced by an alkaline treatment with an aqueous solution of NaOH, KOH or CsOH.
6. The method for producing propylene oxide according to claim 1 , wherein an amount of the gold clusters supported on the support is 0.01 to 10% by weight with respect to the weight of the support.
7. The method for producing propylene oxide according to claim 1 , wherein gold clusters are supported on the aqueous-alkali-treated titanosilicalite support or on the aqueous-alkali-treated mesoporous titanosilicate support by a solid phase grinding method, an impregnation method, a deposition reduction method, a deposition precipitation method or a gas phase grafting method.
8. The method for producing propylene oxide according to claim 1 , wherein the ratio (volume ratio) of propylene to oxygen is 100:1 to 1:100.
9. The method for producing propylene oxide according to claim 2 , wherein the ratio (volume ratio) of propylene to oxygen to water is 1 to 100:1 to 100:0.1 to 10.
10. The method for producing propylene oxide according to claim 3 , wherein the ratio (volume ratio) of propylene to oxygen to hydrogen is 1 to 100:1 to 100:0.1 to 10.
11. The method for producing propylene oxide according to claim 4 , wherein the ratio (volume ratio) of propylene to oxygen to water to hydrogen is 1 to 100:1 to 100:0.1 to 10:0.1 to 10.
12. The method for producing propylene oxide according to claim 1 , wherein the reaction temperature is 50 to 300° C., and the space velocity of the feed gas is 1,000 to 20,000 h −1 ml/g-cat.