Sealant composition for releasable shingle
A sealant composition for roofing shingles that includes a base asphalt, a linear and/or a radial copolymer, oil, and a wax is provided. The linear copolymer has an A-B di-block or an A-B-A tri-block structure. The radial copolymer may have an (A-B) n radial structure, where n is at least 4, or a tri-block (A-B-A) radial structure having from 4 to 8 arms. Blocks A and B may individually represent (1) styrene and butadiene or (2) styrene and isoprene. The oil is a petroleum-based oil that both “softens” the asphalt and reduces the viscosity of the sealant composition. The wax may be a bis-stearamide wax. Additionally, the sealant composition may be reacted with elemental sulfur to crosslink the copolymer blend. The sealant composition seals at temperatures lower than conventional sealants and promotes the easy release of the shingle from a shingle bundle.
1. A roofing shingle comprising:
a tab portion and an upper headlap portion, said shingle being suitable for installing on roofs;
a release tape positioned on a rear portion of said headlap portion; and
a sealant composition positioned on a rear portion of said tab portion, said sealant composition including:
74.0 weight % to about 90.5 weight % of an asphalt-based material;
at least 6 weight % of a blend of at least one linear copolymer and at least one radial copolymer, wherein a ratio of radial copolymer to linear copolymer is from about 6:3 to 2:6;
2.0 weight % to about 7.0 weight % of an oil; and
0.2 weight % to about 5.0 weight % of a bis-stearamide wax,
wherein said linear copolymer has an A-B di-block or an A-B-A tri-block structure;
wherein said radial copolymer is selected from a block copolymer having an (A-B) n radial structure where n is an integer of at least 4 and a block copolymer having a tri-block (A-B-A) radial structure having from 4-8 arms;
wherein said 0.2 weight % to 5.0 weight % of bis-stearamide wax reduces bonding between the sealant and the release tape;
wherein said sealant composition has a viscosity of no more than 1,500 cP at 350° F.; and
wherein said sealant composition seals and bonds shingles at temperatures as low as 40° F.
2. The roofing shingle of claim 1 , wherein said blend of said radial copolymer and said linear copolymer have a styrene content of less than 50% by weight.
3. The roofing shingle of claim 1 , wherein said oil is selected from petroleum-based oils, naphthenic oils, paraffinic oils and combinations thereof.
4. The roofing shingle of claim 1 , wherein said sealant composition reduces the occurrence of said roofing shingles adhering to each other within a packaged bundle of shingles.
5. The roofing shingle of claim 1 , wherein said sealant composition further comprises sulfur as a crosslinking agent.
6. The roofing shingle of claim 1 , wherein said sealant composition includes:
81 weight % to 88 weight % of the asphalt-based material;
6.5 weight % to 14 weight % of the blend of at least one linear copolymer and at least one radial copolymer, wherein the ratio of radial copolymer to linear copolymer is from about 6:3 to 2:6;
about 2.0 weight % to about 7.0 weight % of an oil; and
about 0.5 weight % to about 3.0 weight % of a bis-stearamide wax.
7. A bundle of roofing shingles comprising:
a plurality of pairs of roofing shingles suitable for installing on roofs, each of said roofing shingles in said pair including:
a tab portion and an upper headlap portion;
a release tape positioned on a first portion of said shingle; and
a sealant composition positioned on a second portion of said shingle, wherein said sealant composition comprises:
74.0 weight % to 90.5 weight % of an asphalt-based material;
at least 6 weight % of a blend of at least one linear copolymer and at least one radial copolymer, wherein a ratio of radial copolymer to linear copolymer is from about 6:3 to 2:6;
2.0 weight % to 7.0 weight % of an oil; and
0.2 weight % to 5.0 weight % of a bis-stearamide wax;
wherein said shingles in said pair are positioned such that said sealant on a first shingle of said pair aligns with said release tape of a second shingle in said pair;
wherein said 0.2 weight % to 5.0 weight % of bis-stearamide wax reduces bonding between the sealant and the release tape;
wherein said linear copolymer has an A-B di-block or an A-B-A tri-block structure;
wherein said radial copolymer is selected from a block copolymer having an (A-B) n radial structure where n is an integer of at least 4 and a block co s of mer having a tri-block (A-B-A) radial structure having from 4-8 arms;
wherein said sealant composition has a viscosity of no more than 1,500 cP at 350° F.; and
wherein said sealant composition seals and bonds shingles at temperatures as low as 40° F.
8. The bundle of claim 7 , wherein said sealant releases said first shingle in said pair from said second shingle in said pair.
9. The bundle of claim 7 , wherein said release tape is positioned on a rear portion of said headlap portion.
10. The bundle of claim 9 , wherein said sealant composition is positioned on a rear portion of said tab portion.
11. The bundle of claim 7 , wherein said sealant composition includes from 0.5 weight % to 3.0 weight % of a bis-stearamide wax.