Organic electroluminescent device and display apparatus
View Patent ↗An organic electroluminescent device includes an anode; a cathode; an organic layer including a light-emitting layer and disposed between the anode and the cathode; and an electron transport layer constituting the organic layer, disposed between the cathode and the light-emitting layer, and having a stacked structure including a layer containing a benzimidazole derivative and a layer containing a dibenzimidazole derivative represented by general formula (1): wherein Y 1 to Y 8 each represent a substituted or unsubstituted aryl group having 6 to 60 carbon atoms, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted pyridyl group, a substituted or unsubstituted quinolyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, or a substituted or unsubstituted aliphatic cyclic group, and Y 7 and Y 8 may form a ring through a linking group.
1. An organic electroluminescent device comprising:
an anode;
a cathode; and
an organic layer including at least (i) a light-emitting layer, (ii) a hole supply layer including a hole injection layer, and a hole transport layer and (iii) an electron transport layer, the organic layer between the anode and the cathode,
wherein,
the electron transport layer being located between the cathode and the light-emitting layer,
the electron transport layer has a stacked structure including a layer containing a benzimidazole derivative and a layer containing a dibenzimidazole derivative represented by general formula (1):
where Y 1 to Y 8 each represent a substituted or unsubstituted aryl group having 6 to 60 carbon atoms, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted pyridyl group, a substituted or unsubstituted quinolyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, or a substituted or unsubstituted aliphatic cyclic group, and Y 7 and Y 8 may form a ring through a linking group,
the thickness, [d 1 ], of the electron transport layer, is larger than the total thickness, [d 2 ], of the hole supply layer, and
the ratio of the thickness [d 1 ] of the electron transport layer to the total thickness [da] of the organic layer satisfies the relationship 0.90>[d 1 ]/[da]>0.30.
2. The organic electroluminescent device according to claim 1 , wherein the electron transport layer has a structure in which the layer containing the dibenzimidazole derivative and the layer containing the benzimidazole derivative are stacked in this order from the light-emitting layer side where the layer containing the dibenzimidazole derivative is closer to the light-emitting layer side than the layer containing the benzimidazole derivative.
3. The organic electroluminescent device according to claim 1 , wherein the hole injection layer is between the anode and the light-emitting layer.
4. The organic electroluminescent device according to claim 1 , wherein the thickness [d 1 ] of the electron transport layer is 70 nm or more.
5. The organic electroluminescent device according to claim 1 , wherein the thickness [d 2 ] of the hole supply layer is 60 nm or less.
6. The organic electroluminescent device according to claim 1 , wherein light generated in the light-emitting layer is resonated between the anode and the cathode and extracted from one of the anode and the cathode.
7. The organic electroluminescent device according to claim 1 , wherein the light-emitting layer contains an anthracene derivative.
8. A display apparatus comprising:
an anode;
a cathode; and
an organic layer including at least (i) a light-emitting layer, (ii) a hole supply layer including a hole injection layer and a hole transport layer, and (iii) an electron transport layer, the organic layer located between the anode and the cathode,
wherein,
the electron transport layer is located between the cathode and the light-emitting layer,
the electron transport layer has a structure in which a layer containing a dibenzimidazole derivative represented by general formula (1) and a layer containing a benzimidazole derivative are stacked in this order from the light-emitting layer side, where the layer containing the dibenzimidazole derivative is closer to the light-emitting layer side than the layer containing the benzimidazole derivative,
general formula 1 being:
where Y 1 to Y 8 each represent a substituted or unsubstituted aryl group having 6 to 60 carbon atoms, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted pyridyl group, a substituted or unsubstituted quinolyl group, a substituted or unsubstituted alkyl group having 1 to 20 carbon atoms, a substituted or unsubstituted alkoxy group having 1 to 20 carbon atoms, or a substituted or unsubstituted aliphatic cyclic group, and Y 7 and Y 8 may form a ring through a linking group,
a substrate on which an organic electroluminescent device including the anode, the cathode, and the organic layer disposed between the anode and the cathode is arranged,
the thickness, [d 1 ], of the electron transport layer, is larger than the total thickness, [d 2 ], of the hole supply layer, and
the ratio of the thickness [d 1 ] of the electron transport layer to the total thickness [da] of the organic layer satisfies the relationship 0.90>[d 1 ]/[da]22 0.30.
9. The organic electroluminescent device according to claim 4 , wherein the hole supply layer has a thickness [d 2 ] of 60 nm or less.