Process for producing flexible polyurethane foam, process for producing hot press molded product, and hot press molded product
View Patent ↗To provide a process for producing a flexible polyurethane foam which is excellent in low resiliency, air flow and hot moldability, and a process for producing a hot press molded product by using such a flexible polyurethane foam. Further, the present invention provides a hot press molded product which has a low resiliency and air flow.
1. A process for producing a flexible polyurethane foam, which comprises reacting a polyol composition (P) with a polyisocyanate compound (I) in the presence of an urethane-forming catalyst and a blowing agent, wherein the polyol composition (P) comprises the following polyol (A), the following polyol (B) and the following monool (D), and the ratio of isocyanate-reactive active hydrogen-containing compounds including the polyol composition (P) in the raw material to the polyisocyanate compound (I) is 65 to 85 by isocyanate index, wherein:
Polyol (A) is a polyoxypropylene polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 10 to 90 mgKOH/g, obtained by ring-opening polymerization of only propylene oxide to an initiator (a1);
Polyol (B) is a polyether polyol having an average of from 2 to 3 hydroxyl groups and a hydroxyl value of from 100 to 250 mgKOH/g, obtained by ring-opening polymerization of an alkylene oxide (b2) to an initiator (b1);
Monool (D) is a polyether monool having a hydroxyl value of from 5 to 200 mgKOH/g, obtained by ring-opening polymerization of an alkylene oxide (d2) to an initiator (d1); and
the polyisocyanate compound (I) is a toluene diisocyanate (TDI) mixture comprising at least 20 mass % of 2,6-TDI.
2. The process for producing a flexible polyurethane foam according to claim 1 , wherein the polyol composition (P) is reacted with the polyisocyanate compound (I) in the presence of a foam stabilizer in addition to the urethane-forming catalyst and the blowing agent.
3. The process for producing a flexible polyurethane foam according to claim 1 , wherein the polyol composition (P) further contains the following polyol (C):
Polyol (C) is a polyether polyol having an average of from 2 to 6 hydroxyl groups, a hydroxyl value of from 15 to 99 mgKOH/g and an oxyethylene group content of at least 50 mass % in the total oxyalkylene groups (100 mass %), obtained by ring-opening polymerization of an alkylene oxide (c2) to an initiator (c1).
4. The process for producing a flexible polyurethane foam according to claim 3 , wherein the mass ratio of the polyol (A) in the polyol composition (P) is from 5 to 50 parts by mass, based on the 100 parts by mass of the total mass of the polyol (A), the polyol (B) and the polyol (C).
5. The process for producing a flexible polyurethane foam according to claim 3 , wherein the polyol (A) contains a polyether diol having 2 hydroxyl groups in an amount of from 50 to 100 mass % of the total polyol (A).
6. The process for producing a flexible polyurethane foam according to claim 3 , wherein the mass ratio of the monool (D) in the polyol composition (P) is from 1 to 30 parts by mass per 100 parts by mass of the total mass of the polyol (A), the polyol (B) and the polyol (C).
7. The process for producing a flexible polyurethane foam according to claim 1 , wherein the polyol (A) is a polyoxypropylene polyol obtained by ring-opening polymerization of only propylene oxide to an initiator (al) in the presence of a double metal cyanide complex catalyst.
8. The process for producing a flexible polyurethane foam according to claim 1 , wherein the monool (D) is a polyoxypropylene monool obtained by ring-opening polymerization of only propylene oxide to an initiator (d1).
9. The process for producing a flexible polyurethane foam according to claim 1 , wherein the ring-opening polymerization catalyst for the monool (D) is a double metal cyanide complex catalyst.
10. A process for producing a hot press molded product, which comprises hot press molding a flexible polyurethane foam obtained by the process as defined in claim 1 .
11. The process for producing a flexible polyurethane foam according to claim 1 , wherein the flexible polyurethane foam has a rebound resilience of at most 10%.
12. The process for producing a flexible polyurethane foam according to claim 1 , wherein the flexible polyurethane foam has an air flow of from 30 to 100 L/min.
13. The process for producing a flexible polyurethane foam according to claim 1 , wherein said ratio is from 70 to 85.
14. The process for producing a flexible polyurethane foam according to claim 1 , wherein said ratio is from 75 to 85.
15. The process for producing a flexible polyurethane foam according to claim 1 , wherein the flexible polyurethane foam has a rebound resilience of at most 8%.
16. The process for producing a flexible polyurethane foam according to claim 1 , wherein the flexible polyurethane foam has an air flow of from 40 to 100 L/min.
17. The process for producing a flexible polyurethane foam according to claim 1 , wherein the flexible polyurethane foam has an air flow of from 70 to 100 L/min.