Sterilisable and tough impact polypropylene composition
View Patent ↗The present invention relates to a heterophasic polypropylene composition which is sterilizable and has a high impact strength as well as improved optical properties both before and after a step of heat sterilization. Furthermore, the present invention relates to a film comprising said heterophasic polypropylene composition, and to the use of said composition for the production of a film. Finally, the present invention is directed to the use of such a film as a packaging material for medicals and/or food. The heterophasic polypropylene composition comprises a matrix resin which comprises (A) a propylene homopolymer and (B) a propylene random copolymer; and a dispersed phase which comprises (C) an ethylene-propylene rubber wherein (i) the melting point of the heterophasic polypropylene composition is at least 145° C. and (ii) the content of comonomer in the matrix resin is at least 0.5 wt % based on the entire matrix resin without any additives.
1. Cast film comprising a heterophasic polypropylene composition comprising a matrix resin which comprises
(A) 10-85 wt % of a propylene homopolymer with an MFR 2 of 0.5-20 g/10 min and
(B) 10-85 wt % of a propylene-ethylene random copolymer with an MFR 2 of 0.5-20 g/10 min;
wherein the ethylene content of the matrix resin is 0.5-3.0 wt % based on the entire matrix without any additives;
and a dispersed phase which comprises
(C) 5-30 wt % of an ethylene-propylene rubber,
wherein the xylene soluble content of the heterophasic polypropylene composition has an intrinsic viscosity of 1-2 dl/g and a content of propylene of more than 50 wt %, wherein an impact strength of the cast film is at least 13 J/mm according to ISO 7765-2.
2. Cast film according to claim 1 , wherein the melting point of the heterophasic polypropylene composition is at least 145° C.
3. Cast film according to claim 1 , wherein the cast film is sterilized.
4. Cast film according to claim 1 , wherein the content of comonomer in the matrix resin is at least 0.8 wt % based on the entire matrix resin without any additives.
5. Cast film according to claim 1 having a haze of below 13.5% measured on a 100 μm cast film.
6. Cast film according to claim 1 having a haze of below 17% measured on a 100 μm cast film after a step of heat sterilization at 121° C. for 0.5 h.
7. Cast film according to claim 1 having a Δ(haze) value of 70% or less.
8. Cast film comprising a heterophasic polypropylene composition comprising a matrix resin which comprises
(A) 10-85 wt % of a propylene homopolymer with an MFR 2 of 0.5-20 g/10 min and
(B) 10-85 wt % of a propylene-ethylene random copolymer with an MFR 2 of 0.5-20 q/10 min;
wherein the ethylene content of the matrix resin is 0.5-3.0 wt % based on the entire matrix without any additives;
and a dispersed phase which comprises
(C) 5-30 wt % of an ethylene-propylene rubber,
wherein the xylene soluble content of the heterophasic polypropylene composition has an intrinsic viscosity of 1-2 dl/g and a content of propylene of more than 50 wt %, wherein the impact strength of the cast film after a step of heat sterilization at 121° C. for 0.5 h is at least 9.0 J/mm according to ISO 7765-2.