Beta-nucleated propylene copolymer
View Patent ↗Heterophasic propylene copolymer (HECO) comprising wherein the heterophasic propylene copolymer (HECO) is β-nucleated and the elastomeric phase has an intrinsic viscosity measured in tetraline at 135° C. of equal or below 4.0 dl/g.
1. Heterophasic propylene copolymer (HECO) comprising
(a) a propylene matrix (A) and
(b) an elastomeric copolymer (B) comprising propylene and at least one other C 2 to C 10 α-olefin
wherein
(c) the heterophasic propylene copolymer (HECO) is β-nucleated,
(d) the heterophasic propylene copolymer (HECO) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of below 1.0 g/10min, and
(e) said elastomeric copolymer (B) has an intrinsic viscosity measured in tetraline at 135° C. of equal or below 4.0 dl/g.
2. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) is partially crystallized in the β-modification.
3. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the amount of β-modification of the heterophasic propylene (HECO) copolymer is at least 50%.
4. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the xylene soluble fraction of the propylene matrix (A) is below 2.5 wt.-%.
5. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the propylene matrix (A) is a propylene homopolymer.
6. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the elastomeric copolymer (B) is unimodal.
7. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the elastomeric copolymer (B) comprises propylene and at least one other C 2 to C 10 α-olefin selected from the group consisting of ethylene, 1-butene, 1-pentene, 1-hexene, 1-heptene and 1-octene.
8. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the elastomeric copolymer (B) comprises ethylene.
9. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the elastomeric copolymer (B) comprises propylene and ethylene as the only two α-olefins.
10. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the elastomeric copolymer (B) has a propylene content of equal or below 70 wt.-%.
11. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the elastomeric copolymer (B) is an ethylene propylene rubber (EPR).
12. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the comonomer content of the heterophasic propylene copolymer (HECO) is below 20.0 wt.-% (comonomer/(comonomer+ propylene)).
13. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has an impact strength measured according the Charpy impact test (ISO 179 (1 eA)) at −20° C. of at least 22.0 kJ/m 2 .
14. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) has a flexural modulus measured according to ISO 178 of at least 1000 MPa.
15. Heterophasic propylene copolymer (HECO) according to claim 1 , wherein the heterophasic propylene copolymer (HECO) is multimodal.
16. Heterophasic propylene copolymer according to claim 1 , wherein the heterophasic propylene copolymer (HECO) is a coating layer of a pipe, in particular a steel pipe.
17. Use of a heterophasic propylene copolymer (HECO) according to claim 1 for pipes or parts of a pipes.
18. Use according to claim 17 , wherein the pipe is a steel pipe or a multilayer pipe.
19. Use according to claim 17 , wherein the heterophasic propylene copolymer (HECO) is used as a coating layer for pipes, in particular steel pipes, or as a layer in multilayer pipes.
20. Method for producing an heterophasic propylene copolymer (HECO) comprising the steps of
(a) polymerizing propylene and optionally further comonomer(s) to obtain a propylene matrix (A),
(b) polymerizing propylene and further comonomer(s) to obtain a elastomeric propylene copolymer (B), comprising propylene and at least one other C 2 to C 10 α-olefin
(c) mixing propylene matrix (A) and the elastomeric propylene copolymer (B)
(d) β-nucleating said mixture
wherein
(e) the heterophasic propylene copolymer (HECO) is β-nucleated,
(f) the heterophasic propylene copolymer (HECO) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of below 1.0 g/10min, and
(g) said elastomeric copolymer (B) has an intrinsic viscosity measured in tetraline at 135° C. of equal or below 4.0 dl/g.
21. Method according to claim 20 , wherein the method comprises the steps
(a) polymerizing propylene and optionally further comonomer(s) in at least one reactor to obtain the propylene matrix (A)
(b) transferring said propylene matrix (A) in a further reactor
(c) polymerizing propylene and further comonomer(s) in the presence of said propylene matrix (A) to obtain the elastomeric propylene copolymer (B)
(d) β-nucleating said mixture.
22. A pipe, in particular steel pipe or multilayer pipe, comprising a heterophasic propylene copolymer (HECO) including
(a) a propylene matrix (A) and
(b) an elastomeric copolymer (B) comprising propylene and at least one other C 2 to C 10 α-olefin
wherein
(c) the heterophasic propylene copolymer (HECO) is β-nucleated,
(d) the heterophasic propylene copolymer (HECO) has a melt flow rate MFR 2 (230° C.) measured according to ISO 1133 of below 1.0 g/10min, and
(e) said elastomeric copolymer (B) has an intrinsic viscosity measured in tetraline at 135° C. of equal or below 4.0 dl/g.
23. Pipe according to claim 22 , wherein the heterophasic propylene copolymer (HECO) is a coating layer of the (steel) pipe or a layer of the multilayer pipe.