Low viscosity oligomer oil product, process and composition
View Patent ↗The present invention relates to a low viscosity lubricant process, product, and composition characterized by low Noack volatility, low pour point, useful low temperature viscometrics, and high viscosity index and more particularly concerns a PAO composition having a kinetic viscosity at 100° C. in the range of about 4 cSt.
1. A process for the selective production of synthetic fluid comprising 3.5 to 4.1 cSt viscosity at 100° C., with a Noack volatility weight loss of less than 16%, a Viscosity Index of greater than 120, a Pour Point lower than −50° C., and a viscosity at −40° C. of less than 3000 cSt by:
(a) reacting first alpha olefin, excluding 1-decene, in the presence of a first catalyst to form vinylidene olefin;
(b) reacting said vinylidene olefin with second alpha olefin, excluding 1-decene, in the presence of BF 3 catalyst and a promoter system comprising mixture of at least one aprotic compound with at least one protic compound;
(c) removing residual unreacted monomers and removing unreacted volatile liquids;
(d) hydrogenating bottom product to produce synthetic fluid;
(e) wherein said synthetic fluid comprises 3.5 to 4.1 cSt at 100° C.;
(f) wherein said synthetic fluid comprises production without heavier than 4.1 cSt at 100° C. co-product;
(g) recovering said synthetic fluid.
2. The process of claim 1 wherein first alpha olefin used to form vinylidene olefin selected from the group consisting of linear C 4-20 1-olefin, excluding 1-decene, and combinations thereof.
3. The process of claim 2 wherein said vinylidene olefin comprises a vinylidene content of greater than 70%.
4. The process of claim 1 wherein said first catalyst comprises an alkyl aluminum catalyst, a metallocene catalyst, a bulky ligand late transition metal catalyst, and combinations thereof.
5. The process of claim 1 wherein said first catalyst comprises trialkyl aluminum catalyst.
6. The process of claim 1 wherein said first catalyst comprises metallocene catalyst selected from the metal Periodic Group IVB.
7. The process of claim 1 wherein second alpha olefin selected from the group consisting of linear C 4-20 1-olefin, excluding 1-decene, and combinations thereof.
8. The process of claim 1 wherein the protic promoter is selected from C 1 -C 20 alcohols.
9. The process of claim 8 wherein the alcohol comprises selection from 1-propanol or 1-butanol.
10. The process of claim 1 wherein the aprotic promoter comprises selection from the group consisting of aldehydes, anhydrides, ketones, organic esters, ethers and combinations thereof.
11. The process of claim 10 wherein the aprotic promoter comprises an organic ester selected from the group consisting of C 1 -C 10 alkyl acetates and combinations thereof.
12. The process of claim 11 wherein the aprotic promoter comprises an alkyl acetate.
13. The process of claim 12 wherein the alkyl acetate comprises n-butyl acetate.
14. The process of claim 1 wherein removing residual unreacted monomers comprising distillation.
15. The process of claim 1 wherein said vinylidene olefin comprises purity of at least 80% and comprises dimerization of 1-octene to a C16vinylidene.
16. The process of claim 1 wherein said vinylidene olefin comprises purity of at least 80% and comprises dimerization of 1-octene to a C16vinylindene; wherein said vinylidene olefin comprises reacting C16 vinylidene with 1-tetradecene (C14).
17. The process of claim 1 wherein said vinylidene olefin comprises purity of at least 80% and comprises dimerization 1-octene to a C16vinylidene; wherein said vinylidene olefin comprise reacting C 16 vinylidene with 1-tetradecene (C14);wherein said 1-tetradecene (C 14) comprises a linear terminal purity of at least 70%.
18. The process of claim 1 wherein the said synthetic fluid comprises a mole ratio of C16 vinylidene to 1-tetradecene of between about 1 to about 2.
19. The process of claim 18 wherein the said synthetic fluid comprises a mole ratio of C16 vinylidene to 1-tetradecene of about 1.5.
20. The process of claim 1 wherein the said synthetic fluid mixed with fluid to create a lubricant selected from the group consisting of other synthetic fluid, mineral oil, dispersant, anti-oxidant, anti-wear agent, anti-foam agent, corrosion inhibitor, detergent, seal-swell agent, viscosity improver and combinations thereof.
21. The process of claim 1 , wherein said synthetic fluid contains less than or equal to 5 weight percent of C42to C48+components.