Composition based on polypropylene compounds with styrenic based elastomers
View Patent ↗Polymer composition comprising—a heterophasic propylene copolymer comprising a polypropylene matrix and an elastomeric propylene copolymer comprising at least one comonomer selected from the group consisting of ethylene and C 4 to C 20 α-olefin, and—a styrenic based elastomer(s) (B), wherein the styrene content in each styrenic based elastomer (B) is equal or below 15 wt.-%, and the total amount of the styrenic based elastomer(s) (B) based on the total amount of polymers present in the polymer composition is of 16.0 to 46.0 wt.-%.
1. Polymer composition comprising
(a) a heterophasic propylene copolymer (A) comprising
(a-1) a polypropylene matrix (A-1) and
(a-2) an elastomeric propylene copolymer (A-2) comprising at least one comonomer selected from the group consisting of ethylene and C 4 to C 20 α-olefin,
and
(b) styrenic based elastomer(s) (B),
wherein
(i) the styrene content in each styrenic based elastomer (B) is equal or below 15 wt.-%, and
(ii) the total amount of the styrenic based elastomer(s) (B) based on the total amount of polymers present in the polymer composition is of 16.0 to 46.0 wt.-%,
wherein the polypropylene matrix (A-1) contains a copolymer and wherein the polypropylene matrix is at least bimodal in the comonomer content.
2. Polymer composition according to claim 1 , wherein the styrenic based elastomer(s) (B) is(are) (a) styrene-ethylene/butylene-styrene (SEBS) block copolymer(s) (B-1) and/or (a) hydrogenated styrene isoprene block rubber(s) (B-2).
3. Polymer composition according to claim 1 , wherein the polymer composition comprises as styrenic based elastomer(s) (B) only (a) styrene-ethylene/butylene-styrene (SEBS) block copolymer(s) (B-1) and/or (a) hydrogenated styrene isoprene (SIS) block rubber(s) (B-2).
4. Polymer composition according to claim 1 , wherein the ratio of the melt flow MFR 2 (230° C.) of the heterophasic propylene copolymer (A) to the melt flow MFR 2 (230° C.) of the styrenic based elastomer (B) (MFR 2 (230° C.) (A)/MFR 2 (230° C.) (B)) is ≦1.0.
5. Polymer composition according to claim 1 , wherein the heterophasic propylene copolymer (A) has a xylene cold soluble fraction of 8 to 30 wt.-%.
6. Polymer composition according to claim 5 , wherein the xylene cold soluble fraction of the heterophasic propylene copolymer (A) has an amount of propylene-derived units of at least 52 wt.-%.
7. Polymer composition according to claim 5 , wherein the intrinsic viscosity of the xylene cold soluble fraction of the heterophasic propylene copolymer (A) is equal or below 4.0 dl/g.
8. Polymer composition according to claim 5 , wherein a ratio of the intrinsic viscosity of a xylene cold soluble fraction of the heterophasic propylene copolymer (A) to the intrinsic viscosity of a xylene cold insoluble fraction of the heterophasic propylene copolymer (A) (IV of XCS sol /IV of XCS insol ) is ≦1.0.
9. Polymer composition according to claim 1 , wherein the polypropylene matrix (A-1) is a propylene copolymer (A-1′) comprising at least one comonomer selected from the group consisting of ethylene and C 4 to C 20 α-olefine.
10. Polymer composition according to claim 9 , wherein comonomer content in the propylene copolymer (A-1′) is not more than 5.0 wt.-%.
11. Polymer composition according to claim 1 , wherein the propylene matrix (A-1) comprises
(i) 40 to 60 wt.-% of a first fraction being a propylene polymer, and
(ii) 60 to 40 wt.-% of a second fraction being a propylene random copolymer, wherein the comonomer content between the first fraction and the second fraction differ at least of 2.0 wt.-%.
12. Polymer composition according to claim 1 , wherein the heterophasic propylene copolymer (A) has a melt flow rate MFR 2 (230° C.) of below 4.0 g/10 min.
13. Polymer composition according to claim 1 , wherein the styrenic based elastomer (B) has a melt flow rate MFR 2 (230° C.) of below 6.0 g/10 min.
14. Polymer composition according to claim 1 , wherein the styrenic based elastomer(s) (B) has a density of below 0.900 g/m 3 .
15. Polymer film, wherein said polymer film comprises the polymer composition according to claim 1 .
16. Polymer film according to claim 15 , wherein said film being part of a container.
17. Polymer film according to claim 16 , wherein the container has been subjected to a sterilisation treatment.
18. A process for the production of a polymer composition according to claim 1 , comprising the following steps:
preparing a polypropylene matrix (A-1) constituting a matrix,
preparing an elastomeric propylene copolymer (A-2) comprising at least one comonomer selected from the group consisting of ethylene and C 4 to C 20 α-olefin and dispersing the elastomeric copolymer (A-2) in the propylene copolymer matrix (A-1) to obtain a heterophasic propylene copolymer (A), and subsequently
mixing said heterophasic propylene copolymer (A) with a styrenic based elastomer(s) (B), wherein said styrenic based elastomer(s) (B) is a styrene-ethylene/butylene-styrene (SEBS) block copolymer (B-1) and/or a hydrogenated styrene-vinyl isoprene block rubber (B-2),
wherein
the styrene content in each styrenic based elastomer (B) is equal or below 15 wt.-%, and
the total amount of the styrenic based elastomer(s) (B) based on the total amount of polymers present in the polymer composition is of 16.0 to 46.0 wt-%.
19. The process according to claim 18 , wherein the elastomeric copolymer (A-2) is prepared in the presence of the polypropylene matrix (A-1) constituting the matrix and is in situ dispersed in the matrix.
20. The polymer film according to claim 1 used for the preparation of sterilisable or sterilised films and/or containers, wherein producing a product from said polymer film comprises the step of forming a sterilisable or sterilised film and/or container.
21. Polymer film according to claim 15 , wherein the film has been subjected to a sterilisation treatment.