Perpendicular magnetic recording medium and method of manufacturing the same
View Patent ↗A perpendicular magnetic recording medium includes a substrate, a soft magnetic layer, a pre-underlayer, an underlayer, and a main recording layer serving as a magnetic recording layer. The pre-underlayer contains seed crystal grains that serve as a base for crystal grains of the underlayer, and an addition substance that is added between the seed crystal grains and composed of an element having an atomic radius smaller than that of an element forming the seed crystal grains.
1. A perpendicular magnetic recording medium adapted to record information by a perpendicular magnetic recording system, wherein the perpendicular magnetic recording medium comprises:
a substrate;
a soft magnetic layer formed over the substrate;
a pre-underlayer formed over the soft magnetic layer and containing seed crystal grains, comprising crystal grains of an alloy of Ni and Co, as crystal grains that serve as a base for crystal grains of an upper layer;
an underlayer formed over the pre-underlayer and consisting of crystal grains that control an orientation of crystal grains of an upper layer, wherein the crystal grains consisting of V;
a first non-magnetic onset layer formed directly on an upper surface of the underlayer;
a second non-magnetic onset layer formed directly on an upper surface of the first non-magnetic onset layer;
a magnetic recording layer containing magnetic crystal grains with a crystal structure that is controlled by the underlayer, wherein the magnetic recording layer is formed directly on an upper surface of the second non-magnetic onset layer;
wherein the pre-underlayer contains the seed crystal grains that serve as the base for the crystal grains of the underlayer, and an addition substance consisting of boron that is added between the seed crystal grains, and
wherein the crystal structure of the magnetic crystal grains is same as a crystal structure of the crystal grains in the underlayer, but different from a crystal structure of the seed crystal grains.
2. The perpendicular magnetic recording medium according to claim 1 , wherein the addition substance is a substance that does not chemically react with a material of the soft magnetic layer and the seed crystal grains.
3. The perpendicular magnetic recording medium according to claim 2 , wherein the addition substance is a solid substance.
4. The perpendicular magnetic recording medium according to claim 1 , wherein said pre-underlayer is approximately 10 nm thick.
5. The perpendicular magnetic recording medium according to claim 1 , wherein the second non-magnetic onset layer comprises CoCrPt—Cr 2 O 3 .
6. The perpendicular magnetic recording medium according to claim 1 , wherein the first non-magnetic onset layer is thinner than the second non-magnetic onset layer.
7. The perpendicular magnetic recording medium according to claim 5 , wherein the first non-magnetic onset layer comprises CoCr—SiO 2 .
8. The perpendicular magnetic recording medium according to claim 1 , wherein the seed crystal grains have a body-centered cubic (BCC) crystal structure or a BCC crystal structure close to amorphous.
9. The perpendicular magnetic recording medium according to claim 1 , wherein the magnetic recording layer comprises CoCrPt and an oxide selected from the group consisting of a silicon oxide and a titanium oxide and a ratio of the CoCrPt to the oxide is 9:1 by mol %.
10. The perpendicular magnetic recording medium according to claim 1 further comprises:
a continuous layer formed over the magnetic recording layer, wherein the continuous layer comprises CoCrPtB;
a medium protective layer formed over the continuous layer; and
a lubricating layer formed over the medium protective layer.
11. The perpendicular magnetic recording medium according to claim 10 , wherein a thickness of the continuous layer is 5 nm or less and a thickness of the lubricating layer is 0.5 nm to 2 nm.