Catalyst for removing nitrogen oxides and method for removing nitrogen oxides using the same
View Patent ↗The present invention provides a catalyst which can sufficiently remove nitrogen oxides in an exhaust gas. The catalyst for removing nitrogen oxides to achieve an object of the present invention includes a monolithic support which is coated with a lower layer containing a catalytic component A comprising cerium oxide and an upper layer containing a catalytic component B comprising at least one kind of metal selected from a group consisting of copper, manganese, iron, cobalt and nickel or a compound thereof, and zeolite.
1. A catalyst for removing nitrogen oxides comprising a monolithic support coated with (a) a lower layer containing catalytic component A comprising cerium oxide and at least a refractory inorganic oxide wherein the content of the refractory inorganic oxide contained in said catalytic component A is 2 to 100 parts by mass relative to 100 parts by mass of cerium oxide, and (b) an upper layer containing catalytic component B comprising (b-1) at least one metal selected from a group consisting of copper, manganese, iron, cobalt and nickel or a metal compound thereof, (b-2) zeolite, wherein the content of the metal or the metal compound (the metal/metal compound) contained in the upper layer is 1.0 to 30.0 parts by mass relative to 100 parts by mass of zeolite, and (b-3) at least a refractory inorganic oxide, wherein the content of said refractory inorganic oxide in the upper layer is 10-100 parts by mass relative to 100 parts by mass of the total of the metal/metal compound and zeolite.
2. The catalyst for removing nitrogen oxides according to claim 1 , wherein the content of said catalytic component A is 10 to 100 parts by mass relative to 100 parts by mass of said catalytic component B.
3. The catalyst for removing nitrogen oxides according to claim 1 , wherein said refractory inorganic oxide is selected from a group consisting of aluminium oxide, silicon oxide, phosphorus oxide, titanium oxide and zirconium oxide.
4. The catalyst for removing nitrogen oxides according to claim 1 , wherein the content of said catalytic component A is 50 to 150 g per 1 liter of the monolithic support, and the content of said catalytic component B is 150 to 250 g per 1 liter of the monolithic support.
5. The catalyst for removing nitrogen oxides according to claim 2 , wherein the refractory inorganic oxide is selected from a group consisting of aluminum oxide, silicon oxide, phosphorus oxide, titanium oxide and zirconium oxide.
6. A method for removing nitrogen oxides in an exhaust gas, wherein an exhaust gas containing nitrogen oxides is contacted with the catalyst for removing nitrogen oxides according to claim 1 .
7. The method for removing nitrogen oxides in an exhaust gas according to claim 6 , wherein the catalyst for removing nitrogen oxides is placed in the downstream side of the exhaust gas, and at least one of an oxidation catalyst and a ternary catalyst is placed in the upstream side of the exhaust gas.
8. The method for removing nitrogen oxides in an exhaust gas according to claim 6 , wherein the exhaust gas containing nitrogen oxides with a temperature of 80 to 150° C. is contacted with said catalyst for removing nitrogen oxides.
9. The method for removing nitrogen oxides in an exhaust gas according to claim 6 , wherein said exhaust gas is exhausted from a diesel engine.