Polycarbonate diol
A polycarbonate diol comprising repeating units represented by the following formula (A) and a terminal hydroxy group, 60-100 mol % of the repeating units represented by the formula (A) being repeating units represented by the following formula (B) or (C). The amount of the repeating units represented by the formula (B) is 60-100 mol % based on the total amount of the repeating units represented by the formula (A). The polycarbonate diol has a terminal primary OH ratio of 95% or higher. (A) (In the formula, R represents a C 2-12 divalent aliphatic or alicyclic hydrocarbon.)
1. A polycarbonate diol comprising repeating units represented by the following formula (A) and a terminal hydroxyl group, wherein: from 90 to 100 mol % of the repeating units represented by the formula (A) are repeating units represented by the following formula (B) or (C);
the amount of the repeating units represented by the formula (B) is from 60 to 95 mol % based on the total amount of the repeating units represented by the formula (A);
the polycarbonate diol includes primary and secondary terminal OH groups and has a primary terminal OH ratio of from 96.4% to 99.5%; and
the sum of the primary terminal OH ratio and the secondary terminal OH ratio of the polycarbonate diol is 98.5% or higher and 99.9% or lower; wherein
formula (A) is
in which R represents a divalent aliphatic or alicyclic hydrocarbon having 2 to 12 carbon atoms,
formula (B) is
and formula (C) is
2. The polycarbonate diol according to claim 1 ,
wherein the amount of the repeating units represented by the formula (B) is from 70 to 95 mol % based on the total amount of the repeating units represented by the formula (A); and
the polycarbonate diol has a number-average molecular weight of from 300 to 20,000.
3. A thermoplastic polyurethane, obtained by copolymerizing the polycarbonate diol according to claim 1 and a polyisocyanate.
4. A thermoplastic polyurethane, obtained by copolymerizing the polycarbonate diol according to claim 2 and a polyisocyanate.