Blocking layer
The invention relates to an anode and electrolyte and cathode in direct material contact in fuel cell applications, so that the anode and electrolyte, and the cathode and electrolyte, particularly at temperatures >400° C., can react in a solid chemical manner. Said reaction results in that the material of the anodes can diffuse into the electrolyte and vice versa, and the material of the cathodes can diffuse into the electrolyte or vice versa. The effect thereof is the modification of the electrical energy yield of the fuel cells. In order to prevent said effect, it is proposed according to the invention that a blocking layer is disposed between the electrolyte and anode and electrolyte and cathode and is made of areas having opened and closed pores and that the functional penetration paths for the diffusion are formed by the frame structure thus created.
1. An arrangement for a fuel cell comprising:
a cathode;
an anode;
an electrolyte; and
a blocking layer having pores and pore channels therein such that the blocking layer has a porosity that is graduated and decreases from the electrolyte to the anode or from the electrolyte to the cathode in a direction going into the blocking layer;
wherein the blocking layer is arranged between the electrolyte and the anode or between the electrolyte and the cathode, wherein the blocking layer contacts the anode or the cathode; and
wherein none of the pore channels of the blocking layer extend through the blocking layer that render possible percolation of the electrolyte or cause a short circuit, wherein the fuel cell is a solid oxide fuel cell.
2. A fuel cell according to claim 1 , wherein the blocking layer comprises a ceramic.
3. A fuel cell according to claim 1 , wherein the total porosity of the blocking layer is from 1 to 55% by volume.
4. A fuel cell according to claim 1 , wherein the blocking layer comprises a material and wherein the surface of the material of the blocking layer is enlarged by the porosity.
5. A fuel cell according to claim 1 , wherein there is a lengthening of diffusion stretch for material diffusing into the blocking layer.
6. A fuel cell according to claim 1 , wherein a mechanical tooth construction exists between at least one of the anode, cathode or electrolyte and the blocking layer as a result of material from the anode, cathode or electrolyte penetrating into a pore or pore channel in said blocking layer.
7. A fuel cell according to claim 2 , wherein the ceramic comprises at least one member selected from the group consisting of cerium oxide, technical cerium oxide, doped cerium oxide, zirconium oxide, technical zirconium oxide and doped zirconium oxide.
8. A fuel cell according to claim 2 , wherein the ceramic contains a dopant.
9. A fuel cell according to claim 1 , wherein the blocking layer is applied to part of or all of at least one surface of the electrolyte, the anode or the cathode.
10. A fuel cell according to claim 1 , wherein the blocking layer is applied by screen printing, laminating or coating.
11. A fuel cell comprising:
a cathode;
an anode;
an electrolyte; and
a blocking layer having pores and pore channels therein such that the blocking layer has a porosity; the blocking layer is arranged between the electrolyte and the anode or the cathode; and wherein the blocking layer contacts the anode or the cathode; and
wherein none of the pore channels of the blocking layer extend through the blocking layer, wherein the fuel cell is a solid oxide fuel cell.
12. A fuel cell according to claim 8 , wherein the dopant comprises a member selected from the group consisting of an oxide of Sm and an oxide of Gd.
13. A fuel cell according to claim 2 , wherein the blocking layer is applied to part of or all of at least one surface of the electrolyte, the anode or the cathode.
14. A fuel cell according to claim 1 , wherein the blocking layer is applied to part of or all of at least one surface of the electrolyte.
15. A fuel cell according to claim 1 , wherein the blocking layer is applied to part of or all of at least one surface of the anode.
16. A fuel cell according to claim 1 , wherein the blocking layer is applied to part of or all of at least one surface of the cathode.
17. A fuel cell according to claim 8 , wherein the ceramic comprises at least one member selected from the group consisting of cerium oxide, zirconium and zirconium oxide.
18. A fuel cell according to claim 3 , wherein the blocking layer comprises a ceramic.
19. A fuel cell according to claim 4 , wherein the blocking layer comprises a ceramic.
20. A fuel cell according to claim 5 , wherein the blocking layer comprises a ceramic.
21. A fuel cell according to claim 1 , wherein the blocking layer inhibits solid-state chemical reactions.
22. A fuel cell according to claim 11 , wherein the blocking layer inhibits solid-state chemical reactions.
23. A fuel cell comprising:
a cathode;
an anode;
an electrolyte; and
a blocking layer having pores and pore channels therein such that the blocking layer has a porosity; the blocking layer is arranged between the electrolyte and the anode or the cathode; and wherein the blocking layer is applied to a surface of the anode or a surface of the cathode; and
wherein none of the pore channels of the blocking layer extend through the blocking layer, wherein the fuel cell is a solid oxide fuel cell.