Electrolyte for an electrochemical battery cell
Electrolyte for an electrochemical battery cell that contains sulphur dioxide and a conductive salt. The electrolyte is a gel that is formed with to the involvement of a fluorosulphinate. The invention is also directed to a battery cell that contains such an electrolyte.
1. An electrolyte for an electrochemical battery cell comprising sulphur dioxide and a conductive salt, wherein said electrolyte is a gel that is formed with the involvement of a fluorosulphinate.
2. The electrolyte of claim 1 , wherein the gel forming reaction includes a Lewis-base/Lewis-acid reaction between the fluorosulphinate and a Lewis acid.
3. The electrolyte of claim 1 , wherein the electrolyte contains a metal halide MX, wherein
M is a metal from the third main group of the periodic system, and
X is one of the halogens fluorine, chlorine, bromine or iodine.
4. The electrolyte of claim 1 , wherein the gel contains a solvate of the conductive salt with SO 2 .
5. The electrolyte of claim 1 , wherein the quantity of SO 2 relative to the quantity of conductive salt in the electrolyte is at least 0.1, preferably at least 0.5 mol SO 2 per mol conductive salt.
6. The electrolyte of claim 1 , wherein the conductive salt is selected from the group consisting of aluminates, halides, oxalates, borates, phosphates, arsenates and gallates of an alkali metal, in particular of lithium.
7. An electrochemical battery cell comprising a positive electrode having an active mass, a negative electrode, and the electrolyte of claim 1 .
8. The electrochemical battery cell according of claim 7 , wherein the active mass of the positive electrode contains a metal compound, preferably a metal oxide.
9. The electrochemical battery cell of claim 8 , wherein the active mass of the positive electrode contains a metal oxide of a transition metal M, in particular an element having an atomic number in the range from 22 to 28.
10. The electrochemical battery cell of claim 7 , wherein the active mass of the positive electrode contains an intercalation compound.
11. The electrochemical battery cell of claim 7 , wherein during charging of the cell an active metal is formed at the negative electrode by an electrode reaction, and the active metal is selected from alkali metals, alkaline earth metals, or metals of the second subgroup of the periodic system, the active metal being in particular lithium, sodium, calcium, zinc or aluminium.
12. A method for producing the electrochemical battery cell of claim 7 , comprising the step of forming said gel inside the cell by reacting the fluorosulphinate with an electrolyte, the electrolyte containing SO 2 and a conductive salt.
13. A method for producing the electrochemical battery cell of claim 7 , comprising the step of forming said gel outside the cell, converting said gel to a liquid state by applying mechanical forces, and introducing said electrolyte into the cell as a liquid.