IP Library Granted Patent US 9,656,870
Granted Patent B2
US 9,656,870 · App. 12/747,233 · Granted May 23, 2017

Metal encapsulated dendritic carbon nanostructure, carbon nanostructure, process for producing metal encapsulated dendritic carbon nanostructure, process for producing carbon nanostructure, and capacitor

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Quick Facts
Patent No.
US 9,656,870
App. No.
12/747,233
Granted
May 23, 2017
Kind
B2
Abstract

This invention provides a metal encapsulated dendritic carbon nanostructure comprising a dendritic carbon nanostructure comprising a branched carbon-containing rod-shaped or annular material and a metallic body capsulated in the carbon nanostructure. There is also provided a dendritic carbon nanostructure comprising a branched carbon-containing rod-shaped or annular material.

Claims (33)

1. A dendritic carbon nanostructure having a branched rod-shape or annular-shape, the carbon nanostructure comprising:

a plurality of cavity cells each having a cell wall made of graphene and a cavity enclosed by the cell wall; and

a superficial skin made of graphene having a cell structure, the superficial skin enclosing the plurality of cavity cells,

wherein each of the cavity cells is smaller than a cell of the cell structure of the superficial skin.

2. The dendritic carbon nanostructure as set forth in claim 1 , wherein the dendritic carbon nanostructure is configured as a three-dimensional structure.

3. The dendritic carbon nanostructure as set forth in claim 1 , wherein a length of a branched portion of said dendritic carbon nanostructure is 150 nm or less.

4. The dendritic carbon nanostructure as set forth in claim 1 , wherein a diameter of a branched portion of said dendritic carbon nanostructure is 150 nm or less.

5. The dendritic carbon nanostructure as set forth in claim 1 , having a BET specific surface area of 870 m 2 /g or more.

6. The dendritic carbon nanostructure as set forth in claim 5 , wherein said BET specific surface area is 1300 m 2 /g or more.

7. A pellet comprising a carbon nanostructure as set forth in claim 1 , said carbon nanostructure being pressed.

8. A carrier for supporting a catalyst comprising a carbon nanostructure as set forth in claim 1 .

9. A gas molecule storage material comprising a carbon nanostructure as set forth in claim 1 .

10. A capacitor comprising a pair of electrodes, an electrolyte fluid located between said pair of electrodes, a separator positioned in said electrolyte fluid,

wherein at least one of said electrodes comprises a dendritic carbon nanostructure having a branched rod-shape or annular-shape,

wherein the dendritic carbon nanostructure comprises:

a plurality of cavity cells each having a cell wall made of graphene and a cavity enclosed by the cell wall; and

a superficial skin made of graphene having a cell structure, the superficial skin enclosing the plurality of cavity cells,

wherein each of the cavity cells is smaller than a cell of the cell structure of the superficial skin.

11. The capacitor as set forth in claim 10 , wherein the dendritic carbon nanostructure is configured as a three-dimensional structure.

12. The capacitor as set forth in claim 10 , wherein a length of a branched portion of said dendritic carbon nanostructure is 150 nm or less.

13. The capacitor as set forth in claim 10 , wherein a diameter of a branched portion of said dendritic carbon nanostructure is 150 nm or less.

14. The capacitor as set forth in claim 10 , wherein the dendritic carbon nanostructure has a BET specific surface area of 870 m 2 /g or more.

15. The capacitor as set forth in claim 14 , wherein said BET specific surface area is 1300 m 2 /g or more.

16. The capacitor as set forth in claim 10 , wherein said dendritic carbon nanostructure is a carbon obtained through a thermal treatment for a metal acetylide dendritic crystalline body.

17. The capacitor as set forth in claim 16 , wherein said metal acetylide crystalline body is configured as a metal encapsulated dendritic carbon nanostructure containing a metal and a carbon by contacting an acetylene gas with a solution containing said metal or a salt of said metal at a gas-liquid interface thereof while an ultrasonic wave is applied to said solution.

18. The capacitor as set forth in claim 16 , wherein said solution is agitated when said acetylene gas is contacted with said solution at said gas-liquid interface thereof.

19. The capacitor as set forth in claim 16 , wherein said thermal treatment for said metal acetylide dendritic crystalline body includes a first thermal treatment for segregating carbon elements on said metal acetylide dendritic crystalline body to form a carbon-covering metal acetylide dendritic nanostructure and a second thermal treatment for phase-separating metal elements encapsulated in said carbon-covering metal acetylide dendritic nanostructure.

20. The capacitor as set forth in claim 19 , wherein a solving and washing treatment is conducted for a carbon nanostructure intermediary body obtained through the phase-separation of said metal elements from said carbon-covering metal acetylide dendritic nanostructure to remove a remnant of said metal elements.

21. The capacitor as set forth in claim 19 , wherein said first thermal treatment is conducted within a temperature range of 60° C. to 80° C.

22. The capacitor as set forth in claim 19 , wherein said second thermal treatment is conducted within a temperature range of 160° C. to 200° C. continuously following said first thermal treatment.

23. The capacitor as set forth in claim 19 , wherein a third thermal treatment using a hot water is conducted for said dendritic carbon nanostructure.

24. The capacitor as set forth in claim 23 , wherein said third thermal treatment is conducted within a temperature range of 80° C. to 100° C.

25. The capacitor as set forth in claim 17 , wherein said metal or said salt are silver (Ag) or silver salt.

Assignments (3)
CHANGE OF NAME AND ADDRESS Recorded Jul 24, 2020
From: NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.
To: NIPPON STEEL CHEMICAL & MATERIAL CO., LTD.
Reel/Frame 053309/0758 →
CHANGE OF NAME Recorded Mar 20, 2013
From: NIPPON STEEL CHEMICAL CO., LTD.
To: NIPPON STEEL & SUMIKIN CHEMICAL CO., LTD.
Reel/Frame 030049/0771 →
ASSIGNMENT OF ASSIGNOR'S INTEREST Recorded Dec 2, 2010
From: NISHI, NOBUYUKI; NUMAO, SHIGENORI; JUDAI, KEN; NISHIJO, JUNICHI; MIZUUCHI, KAZUHIKO
To: NIPPON STEEL CHEMICAL CO., LTD.; INTER-UNIVERSITY RESEARCH INSTITUTE CORPORATION, NATIONAL INSTITUTES OF NATURAL SCIENCES
Reel/Frame 025438/0269 →