Color conversion film and multicolor-emitting, organic electroluminescent device comprising the color conversion film
View Patent ↗A color conversion film is disclosed that absorbs light from an organic electroluminescent part emitting blue-green light and converts the light to visible light at a longer wavelength. The color conversion film includes two different dyes. A first dye is a polymer dye with an average molecular weight of 1000 to 1,000,000 that absorbs light incident on the color conversion film and transfers the energy of the light to a second dye. The second dye is a dye that receives the energy from the first dye and emits light. With a multicolor-emitting, organic electroluminescent device including the color conversion film, it is possible to achieve excellent conversion efficiency without increasing the thickness of the color conversion film as in a conventional device using a binder resin.
1. A color conversion film that absorbs light from an organic electroluminescent part emitting blue-green light and converts the light to visible light at a longer wavelength, the color conversion film, comprising:
a first dye and a second dye that are different,
wherein the first dye is a polymer dye having an average molecular weight of 1000 to 1,000,000 and having properties including absorbing light incident on the color conversion film and transferring the absorbed energy of the light to the second dye without emitting light, and
wherein the second dye is a dye that receives the energy from the first dye and emits light.
2. The color conversion film according to claim 1 , wherein the second dye is a polymer dye having an average molecular weight of 1000 to 1,000,000.
3. The color conversion film according to claim 1 , wherein the second dye is a low-molecular-weight dye having an average molecular weight of less than 1000.
4. The color conversion film according to claim 1 , wherein the first dye is an oligomer made up of fluorescent emitting cores bound to each other by non-covalent binding groups.
5. The color conversion film according to claim 4 , wherein the first dye has an absorption spectrum having a maximum wavelength of 400 to 500 nm and a fluorescence spectrum having a maximum wavelength of 500 to 550 nm.
6. The color conversion film according to claim 4 , wherein the second dye has an absorption spectrum having a maximum wavelength of 500 to 550 nm, and a fluorescence spectrum having a maximum wavelength of 550 to 650 nm.
7. The color conversion film according to claim 4 , wherein the second dye is present in an amount of 10 wt % or less of the color conversion film.
8. The color conversion film according to claim 4 , wherein the color conversion film is a coated film formed by a coating method.
9. The color conversion film according to claim 2 , wherein the first dye is an oligomer made up of fluorescent emitting cores bound to each other by non-covalent binding groups.
10. The color conversion film according to claim 3 , wherein the first dye is an oligomer made up of fluorescent emitting cores bound to each other by non-covalent binding groups.
11. A multicolor emitting organic electroluminescent device, comprising:
a pair of electrodes at least one of which is a transparent electrode;
an organic electroluminescent layer sandwiched between the pair of electrodes; and a color conversion film a first dye and a second dye that are different,
wherein the first dye is a polymer dye having an average molecular weight of 1000 to 1,000,000 and having properties including absorbing light incident on the color conversion film and transferring the absorbed energy of the light to the second dye without emitting light, and
wherein the second dye is a dye that receives the energy from the first dye and emits light.
12. The multicolor emitting organic electroluminescent device according to claim 11 , wherein the second dye is a polymer dye having an average molecular weight of 1000 to 1,000,000.
13. The multicolor emitting organic electroluminescent device according to claim 11 , wherein the second dye is a low-molecular-weight dye having an average molecular weight of less than 1000.
14. The multicolor emitting organic electroluminescent device according to claim 11 , wherein the first dye is an oligomer made up of light emitting cores bound to each other by non-covalent binding groups.
15. The multicolor emitting organic electroluminescent device according to claim 14 , wherein the first dye has an absorption spectrum having a maximum wavelength of 400 to 500 nm and a fluorescence spectrum having a maximum wavelength of 500 to 550 nm.
16. The multicolor emitting organic electroluminescent device according to claim 14 , wherein the second dye has an absorption spectrum having a maximum wavelength of 500 to 550 nm, and a fluorescence spectrum having a maximum wavelength of 550 to 650 nm.
17. The multicolor emitting organic electroluminescent device according to claim 14 , wherein the second dye is present in an amount of 10 wt % or less of the color conversion film.
18. The multicolor emitting organic electroluminescent device according to claim 14 , wherein the color conversion film is a coated film formed by a coating method.
19. The multicolor emitting organic electroluminescent device according to claim 12 , wherein the first dye is an oligomer made up of light emitting cores bound to each other by non-covalent binding groups.
20. The multicolor emitting organic electroluminescent device according to claim 13 , wherein the first dye is an oligomer made up of light emitting cores bound to each other by non-covalent binding groups.