Cross-linkable fluoroelastomer excellent in cross-linkability and method for its production
View Patent ↗A cross-linkable fluoroelastomer remarkably excellent in cross-linkability and a method for its production, a fluoroelastomer composition excellent in the cross-linked physical properties, and a cross-linked rubber. A cross-linkable fluoroelastomer having a Mooney viscosity of from 20 to 300, obtainable by heat-treating a mixture of a fluoroelastomer (A), an organic peroxide (B) and at least one additive (C) selected from the group consisting of a C 12-28 higher fatty acid, a metal salt of a C 12-28 higher fatty acid, an ester of a C 12-28 higher fatty acid, an amide of a C 12-28 higher fatty acid and a C 12-28 higher aliphatic alcohol, at a temperature of from 110 to 380° C.
1. A method for producing a cross-linkable fluoroelastomer, which comprises heat-treating a mixture of a fluoroelastomer (A), an organic peroxide (B) and at least one additive (C) selected from the group consisting of a C 12-28 higher fatty acid, a metal salt of a C 12-28 higher fatty acid, an ester of a C 12-28 higher fatty acid, and an amide of a C 12-28 higher fatty acid and a C 12-28 higher aliphatic alcohol, at a temperature of from 110 to 380° C. to produce said cross-linkable fluoroelastomer, wherein the cross-linkable fluoroelastomer has an absorption peak at from 1640 to 1700 cm −1 , wherein the peak intensity of the absorption at from 1640 to 1700 cm −1 of the infrared absorption spectrum as represented by absorbance of a hot pressed sample having a thickness of 0.2 mm is from 0.05 to 1.5, and wherein the fluoroelastomer (A) has no absorption peak at from 1640 to 1700 cm −1 .
2. The method for producing a cross-linkable fluoroelastomer according to claim 1 , wherein the cross-linkable fluoroelastomer produced has a Mooney viscosity of from 20 to 300.
3. The method for producing a cross-linkable fluoroelastomer according to claim 1 , wherein the additive (C) is a C 12-28 higher fatty acid and/or its metal salt.
4. The method for producing a cross-linkable fluoroelastomer according to claim 1 , wherein the blend ratio of fluoroelastomer (A)/organic peroxide (B)/additive (C) in the mixture is 100/0.1 to 10/0.1 to 10 (mass ratio).
5. The method for producing a cross-linkable fluoroelastomer according to claim 1 , wherein the fluoroelastomer (A) is a tetrafluoroethylene/propylene copolymer.
6. The method for producing a cross-linkable fluoroelastomer according to claim 1 , wherein the temperature for half life of one minute of the organic peroxide (B) is from 110 to 200° C.
7. The method for producing a cross-linkable fluoroelastomer according to claim 1 , which comprises kneading and heat-treating a mixture of a fluoroelastomer (A), an organic peroxide (B) and at least one additive (C) selected from the group consisting of a C 12-28 higher fatty acid, a metal salt of a C 12-28 higher fatty acid, an ester of a C 12-28 higher fatty acid, an amide of a C 12-28 higher fatty acid and a C 12-28 higher aliphatic alcohol, at a temperature of from 110 to 380° C. by means of an extruder.
8. The method according to claim 1 , further comprising mixing the cross-linkable fluoroelastomer with a vulcanizer (D) and a vulcanization assistant (E) to produce a cross-linkable fluoroelastomer composition.
9. The method according to claim 8 , further comprising cross-linking the cross-linkable fluoroelastomer composition.
10. The method according to claim 9 , wherein said crosslinking is accomplished by applying an ionizing radiation to the cross-linkable fluoroelastomer composition.
11. The method for producing a cross-linkable fluoroelastomer according to claim 1 , wherein the cross-linkable fluoroelastomer produced has a Mooney viscosity of from 30 to 200.
12. The method for producing a cross-linkable fluoroelastomer according to claim 11 , wherein fluoroelastomer (A) has no carbon-carbon unsaturated bonds.
13. The method for producing a cross-linkable fluoroelastomer according to claim 12 , wherein the fluoroelastomer (A) is a tetrafluoroethylene/propylene copolymer.
14. The method for producing a cross-linkable fluoroelastomer according to claim 1 , wherein fluoroelastomer (A) has no carbon-carbon unsaturated bonds.