Process for the preparation of halo-olefins

1. A process for preparing a haloolefin comprising:

contacting a halogenated hydrocarbon with a metal dehalogenating agent, in a solvent, in the presence of a phase transfer catalyst, under conditions sufficient to dehalogenate said halogenated hydrocarbon to produce a product stream comprising said haloolefin.

2. The process of claim 1 , wherein said haloolefin is selected from the group consisting of chlorotrifluoroethylene, tetrafluoroethylene, difluoroethylene and vinyl chloride.

3. The process of claim 2 wherein said halo-olefin in chlorotrifluoroethylene.

4. The process of claim 1 , wherein said halogenated hydrocarbon is selected from the group consisting of trichlorotrifluoroethane, trichloroethane, dichlorodifluorethane and dichlorotetrafluoroethane.

5. The process of claim 4 , wherein said halogenated hydrocarbon is trichlorotrifluoroethane.

6. The process of claim 1 , wherein said dehalogenating agent is selected from the group consisting of zinc, tin, manganesium, iron, and aluminum.

7. The process of claim 6 , wherein said dehalogenating agent is zinc.

8. The process of claim 1 , wherein said phase transfer catalyst is selected from the group consisting of crown ethers, onium salts, cryptates and polyalkylene glycols and derivatives thereof, and mixtures thereof.

9. The process of claim 8 , wherein said phase transfer catalyst is an onium salt.

10. The process of claim 8 , wherein said phase transfer catalyst is a quaternary ammonium salt.

11. The process of claim 10 , wherein said quaternary ammonium salt is a tetrabutylammonium bromide.