Process for preparing diaryl carbonates or alkyl aryl carbonates from dialkyl carbonates
View Patent ↗The invention relates to a process for preparing diaryl carbonates and/or alkyl aryl carbonates from dialkyl carbonates and aromatic hydroxy compounds using a reactive dividing wall column.
1. A process for preparing an alkyl aryl carbonate and/or a diaryl carbonate comprising reacting a dialkyl carbonate and an aromatic hydroxy compound in the presence of a catalyst in a reactive distillation column, wherein said reactive distillation column is divided by one or more separation devices which are effective in the longitudinal direction and completely or partially prevent transverse mixing of liquid and/or vapour streams into a feed side (Z) in which a reaction zone is located and an offtake side (E), wherein a stream ( 21 ) comprising said aromatic hydroxy compound and a stream ( 22 ) comprising said dialkyl carbonate are fed to said feed side (Z) and at the same time one or more middle-boiling fractions which optionally comprise reactants and/or reaction products are removed in gaseous or liquid form from the offtake side (E).
2. The process of claim 1 , wherein said one or more separation devices completely prevent transverse mixing of liquid and/or vapour streams.
3. The process of claim 1 , wherein said stream ( 21 ) is fed above said reaction zone and stream ( 22 ) is fed below said reaction zone.
4. The process of claim 1 , wherein said aromatic hydroxy compound is phenol, said dialkyl carbonate is dimethyl carbonate or diethyl carbonate, and said diaryl carbonate is diphenyl carbonate.
5. The process of claim 1 , wherein said reaction is homogeneously catalyzed.
6. The process of claim 1 , wherein said stream ( 21 ) comprises said catalyst.
7. The process of claim 1 , wherein said stream ( 21 ) and/or said stream ( 22 ) containing the dialkyl carbonate are fed in gaseous or heated form.
8. The process of claim 1 , wherein said stream ( 21 ) is introduced in liquid form or with only a small proportion of vapour and said stream ( 22 ) is fed in gaseous or superheated form.
9. The process of claim 1 , wherein at least one further section (K 1 TLO) which comprises no catalyst or a maximum of 1% by weight of catalyst is present on the feed side (Z) above said reaction zone.
10. The process of claim 9 , wherein said section K 1 TLO is equipped with at least one intermediate condenser and the heat of condensation obtained by condensation in said condenser is returned either directly or indirectly to the process.
11. The process of claim 1 , wherein at least one further section (K 1 TLU) is present on the feed side (Z) below the reaction zone.
12. The process of claim 11 , wherein said section K 1 TLU is equipped with at least one intermediate condenser.
13. The process of claim 10 , wherein said at least one intermediate condenser is integrated into said reactive distillation column or present as a separate intermediate condenser outside said reactive distillation column.
14. The process of claim 12 , wherein said at least one intermediate condenser is integrated into said reactive distillation column or present as a separate intermediate condenser outside said reactive distillation column.
15. The process of claim 1 , wherein said reaction is carried out at a temperature in the range of from 100 to 300° C. and a pressure in the range of from 0.5 to 20 bar.
16. The process of claim 1 , wherein the reaction zone comprises from 5 to 100 theoretical plates, wherein the reaction is carried out at a temperature in the range of from 180 to 245° C. and a pressure in the range from 2 to 10 bar.