Polypropylene compositions
View Patent ↗A mineral-filled, polypropylene composition comprises (i) a coupled, impact propylene polymer, and (ii) at least 0.5 weight percent (wt %) based on the weight of the composition of at least one of calcium carbonate and talc. The compositions are useful in the manufacture of three-layer pipe comprising (A) a first or outer non-foam layer; (B) a second or middle foam layer; and (C) a third or inner non-foam layer.
1. A mineral-filled, polypropylene composition comprising (i) a coupled blend of a polypropylene homopolymer and an impact modifier, (ii) greater than 53 weight percent (wt %) based on the weight of the composition of at least one mineral filler, and (iii) a foaming agent.
2. The composition of claim 1 in which the mineral filler comprises a platelet filler and a non-platelet filler, and the amount of mineral filler in the composition is from 55 to 60 wt % based on the total weight of the composition.
3. The composition of claim 2 in which the platelet filler and the non-platelet filler are present in a weight ratio between 1:30 and 1:3.
4. The composition of claim 3 in which the mean particle size of the non-platelet filler is from 0.2 to 3 microns, the mean particle size of the platelet filler is from 0.1 to 3 microns, and the length to thickness (L/T) ratio of the platelet filler is between 1 and 50.
5. The composition of claim 1 in which the polypropylene homopolymer has a crystallinity of at least 50 percent.
6. The composition of claim 5 in which the impact modifier comprises from 8 to 40 wt % of the coupled blend.
7. An article comprising the composition of claim 1 .
8. The article of claim 7 in the form of a pipe.
9. The article of claim 8 , wherein the pipe is of three layers comprising (a) a first or outer or outside non-foam layer; (b) a second or middle or core foam layer; and (c) a third or inner or inside non-foam layer.
10. A mineral-filled, polypropylene composition comprising (i) a coupled blend of polypropylene homopolymer having a crystallinity of at least 50 percent, and an impact modifier comprising from 8 to 40 wt % of the coupled blend, (ii) at least 25 weight percent (wt %) based on the weight of the composition of at least one mineral filler, and (iii) a foaming agent,
wherein the coupled impact propylene copolymer, or coupled blend of polypropylene homopolymer and impact modifier, is formed by the reaction of (a) a coupling agent having at least two reactive groups that are each capable of forming a carbene or nitrene group, and (b) an impact propylene polymer.
11. The composition of claim 10 in which the coupling agent is an azide.
12. The composition of claim 10 in which the mineral filler comprises a platelet filler and a non-platelet filler, and the amount of mineral filler in the composition is from 28 to 60 wt % based on the total weight of the composition.
13. The composition of claim 12 in which the platelet filler and the non-platelet filler are present in a weight ratio between 1:30 and 1:3.
14. The composition of claim 13 in which the mean particle size of the non-platelet filler is from 0.2 to 3 microns, the mean particle size of the platelet filler is from 0.1 to 3 microns, and the length to thickness (L/T) ratio of the platelet filler is between 1 and 50.
15. An article comprising the composition of claim 10 .
16. The article of claim 15 in the form of a pipe.
17. The article of claim 16 , wherein the pipe is of three layers comprising (a) a first or outer or outside non-foam layer; (b) a second or middle or core foam layer; and (c) a third or inner or inside non-foam layer.