Procatalyst composition with silyl glutarate and method
View Patent ↗Disclosed are procatalyst compositions having an internal electron donor which includes a silyl glutarate and optionally an electron donor component. Ziegler-Natta catalyst compositions containing the present procatalyst compositions exhibit strong activity and produce propylene-based olefins with high isotacticity.
1. A catalyst composition comprising:
a procatalyst comprising a combination of a magnesium moiety, a titanium moiety and an internal electron donor comprising a silyl glutarate; and
a cocatalyst.
2. A The catalyst composition of claim 1 comprising:
a silyl glutarate having the structure (I)
wherein R 1 -R 8 are the same or different, each of R 1 and R 2 is selected from the group consisting of hydrogen and a saturated hydrocarbyl group having 1-6 carbon atoms, each of R 3 -R 6 is selected from the group consisting of hydrogen and a hydrocarbyl group having 1-10 carbon atoms, each of R 7 and R 8 is selected from a hydrocarbyl group having 1-2 carbon atoms, and R 1 , R 2 , R 7 and R 8 are simultaneously not a methyl group.
3. The catalyst composition of claim 2 wherein each of R 1 and R 2 is selected from a saturated hydrocarbyl group having 1-4 carbon atoms.
4. The catalyst composition of claim 2 wherein the silyl glutarate is a member selected from the group consisting of diethyl 2,2′-(diisopropylsilanediyl)diacetate.
5. The catalyst composition of claim 1 wherein the silyl glutarate has the structure (I)
wherein R 1 -R 8 are the same or different, each of R 1 -R 6 is selected from the group consisting of hydrogen, a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, and combinations thereof, and each of R 7 -R 8 is selected from the group consisting of a substituted hydrocarbyl group having 1 to 20 carbon atoms, an unsubstituted hydrocarbyl group having 1 to 20 carbon atoms, and combinations thereof.
6. The catalyst composition of claim 5 wherein R 1 and R 2 are the same or different and each is selected from the group consisting of hydrogen, a C 1 -C 6 alkyl group, and combinations thereof.
7. The catalyst composition of claim 5 wherein R 1 and R 2 are the same or different and each is selected from the group consisting of a methyl group, an ethyl group, a propyl group, an isopropyl group, a butyl group, an isobutyl group and combinations thereof.
8. The catalyst composition of claim 5 wherein each of R 1 and R 2 is a methyl group.
9. The catalyst composition of claim 5 wherein each of R 1 and R 2 is an isopropyl group.
10. The catalyst composition of claim 5 wherein each of R 1 and R 2 is an isobutyl group.
11. The catalyst composition of claim 5 wherein R 7 and R 8 are the same or different and each is selected from the group consisting of a C 1 -C 6 alkyl group.
12. The catalyst composition of claim 5 wherein each of R 7 and R 8 is an ethyl group.
13. The catalyst composition of claim 12 wherein each of R 1 and R 2 is a methyl group.
14. The catalyst composition of claim 12 wherein each of R 1 and R 2 is an isopropyl group.
15. The catalyst composition of claim 12 wherein each of R 1 and R 2 is an isobutyl group.
16. The catalyst composition of claim 5 wherein the internal electron donor comprises an electron donor component selected from the group consisting of a phthalate, ethyl benzoate, a diether, and combinations thereof.
17. The catalyst composition of claim 5 comprising a member selected from the group consisting of an external electron donor, a mixed external electron donor, an activity limiting agent, and combinations thereof.
18. The catalyst composition of claim 17 wherein the external electron donor comprises an alkoxysilane.
19. The catalyst composition of claim 17 comprising an activity limiting agent selected from the group consisting of a carboxylic acid ester, a diether, a diol ester, and combinations thereof.
20. A process for producing an olefin-based polymer comprising:
contacting, under polymerization conditions, an olefin with the catalyst composition of claim 1 ; and
forming an olefin-based polymer.