Process for removing phosphorus-containing colloids and their precursors from iron chloride solutions
View Patent ↗The disclosure provides a process for removing phosphorus-containing colloids and their precursors from an iron chloride solution comprising: (a) heating the iron chloride solution comprising impurities selected from the group consisting of phosphorus-containing colloid, phosphorus-containing colloid precursor, and mixtures thereof, at a temperature of about 100° C. to about 300° C., at least autogenous pressure and for a period of time sufficient to transform the impurities into a filterable solid; and (b) separating the solid from the iron chloride solution. In one embodiment, the iron chloride solution is a byproduct of the chloride process for making titanium dioxide.
1. A process for removing phosphorus-containing colloids and their precursors from an iron chloride solution comprising:
(a) heating the iron chloride solution comprising impurities selected from the group consisting of phosphorus-containing colloid, phosphorus-containing colloid precursor, and mixtures thereof, at a temperature of about 100° C. to about 300° C., and at-least autogenous pressure to transform the impurities into a filterable solid; and
(b) separating the filterable solid from the iron chloride solution.
2. The process of claim 1 wherein the separating of the filterable solid is accomplished by filtering, settling, or centrifuging.
3. The process of claim 1 wherein the heating is conducted at a temperature of about 200° C. to about 250° C.
4. The process of claim 1 wherein the at least autogenous pressure is about 500 to about 1400 psig.
5. The process of claim 4 wherein the at least autogenous pressure is about 500 to about 800 psig.
6. The process of claim 1 wherein the iron chloride solution comprising impurities is heated for about 1 to about 120 minutes.
7. The process of claim 6 wherein the iron chloride solution comprising impurities is heated for about 3 to about 30 minutes.
8. A process for removing impurities selected from the group consisting of phosphorus-containing colloid, phosphorus-containing colloid precursor and mixtures thereof, from an iron chloride solution having an iron concentration of about 50 to about 250 grams/liter comprising:
(a) reacting more comprising metal oxides with chlorine and a carbon compound at a temperature of about 900° C. to about 1300° C. to form a gaseous stream comprising the chlorides of the metal and off gases comprising carbon monoxide;
(b) cooling the gaseous stream to form solids comprising iron chloride and a compound selected from the group consisting of phosphorus-containing compound, niobium compound, titanium compound, zirconium compound and mixtures thereof;
(c) quenching the solids formed in step (b) to form an iron chloride solution, having an iron concentration of about 50 to about 250 grams/liter, and comprising impurities selected from the group consisting of a phosphorus-containing colloid, phosphorus-containing colloid precursor, and mixtures thereof;
(d) heating the iron chloride solution comprising the impurities, in a vessel, at a temperature of about 100° C. to about 300° C., and at least autogenous pressure to transform phosphorus-containing colloid, phosphorus-containing colloid precursor, and mixtures thereof into a filterable solid; and
(e) separating the filterable solid from the iron chloride solution.
9. The process of claim 8 wherein the carbon compound is coke.
10. The process of claim 8 wherein the solids are separated in a spray condenser or a cyclone.
11. The process of claim 8 wherein the quenching is accomplished by adding dilute hydrochloric acid or water to the solids.
12. The process of claim 8 wherein the separating of the solid in step (e) is accomplished by filtering, settling, or centrifuging.
13. The process of claim 8 wherein the heating is conducted at a temperature of about 200° C. to about 250° C.
14. The process of claim 8 wherein the at least autogenous pressure is about 200 to about 1400 psig.
15. The process of claim 14 wherein the at least autogenous pressure is about 500 to about 800 psig.
16. The process of claim 8 wherein the iron chloride solution comprising impurities is heated for about 1 to about 120 minutes.
17. The process of claim 16 wherein the iron chloride solution comprising impurities is heated for about 3 to about 30 minutes.
18. The process of claim 8 wherein the vessel is a substantially closed vessel that is selected from the group consisting of an autoclave and a continuous flow pipeline reactor.
19. The process of claim 8 wherein the phosphorus-containing compound is selected from the group consisting of chlorides of phosphorus, oxychlorides of phosphorus, fine particles of ore comprising phosphorus, and mixtures thereof.