Liquid Crystal composition and liquid crystal display device
View Patent ↗The invention is to provide a liquid crystal composition that satisfies at least one characteristic among characteristics such as a high maximum temperature of a nematic phase, a low minimum temperature of a nematic phase, a small viscosity, a large optical anisotropy, a large dielectric anisotropy, a large specific resistance, a high stability to ultraviolet light and a high stability to heat, or that is suitably balanced regarding at least two of the characteristics. The invention is to provide an AM device that has a short response time, a large voltage holding ratio, a large contrast ratio, a long service life and so forth.
1. A liquid crystal composition having a nematic phase that comprises two components, wherein the first component is at least one compound selected from the group of compounds represented by formulas (1-1), (1-3), (1-4), (1-5), (1-6), (1-7), (1-8) and (1-9), the second, component is at least one compound selected from the group of compounds represented by formula (2):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 2 and R 3 are each independently alkenyl having 2 to 12 carbons; X 1 , X 2 , X 3 , X 4 , X 5 , X 6 , X 7 , X 8 and X 9 are each independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy.
2. The liquid crystal composition according to claim 1 , wherein the first component is at least one compound selected from the group of compounds represented by formula (1-1).
3. The liquid crystal composition according claim 1 , wherein the ratio of the first component is in the range of approximately 5% to approximately 40% by weight and the ratio of the second component is in the range of approximately 20% to approximately 95% by weight, based on the total weight of the liquid crystal composition.
4. The liquid crystal composition according to claim 1 , wherein the composition further comprises at least one compound selected from the group of compounds represented by formula (3) as a third component:
wherein R 4 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; R 5 is alkyl having 1 to 12 carbons or alkoxy having 1 to 12 carbons; ring C and ring D are each independently 1,4-cyclohexylene, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene or 2,5-difluoro-1,4-phenylene; Z 3 is independently a single bond, ethylene or carbonyloxy; and p is 1, 2 or 3.
5. The liquid crystal composition according to claim 4 , wherein the third component is at least one compound selected from the group of compounds represented by formulas (3-1) to (3-11):
wherein R 4 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; and R 5 is alkyl having 1 to 12 carbons or alkoxy having 1 to 12 carbons.
6. The liquid crystal composition according to claim 5 , wherein the third component is at least one compound selected from the group of compounds represented by formula (3-1).
7. The liquid crystal composition according to claim 4 , wherein the ratio of the third component is in the range of approximately 5% to approximately 60% by weight based on the total weight of the liquid crystal composition.
8. The liquid crystal composition according to claim 1 , wherein the composition further comprises at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring E is independently 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or pyrimidine-2,5-diyl; Z 4 is independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are each independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy; and k is 1 or 2.
9. The liquid crystal composition according to claim 4 , wherein the composition further comprises at least one compound selected from the group of compounds represented by formula (4) as a fourth component:
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine; ring E is independently 1,4-cyclohexylene, 1,3-dioxane-2,5-diyl, 1,4-phenylene, 2-fluoro-1,4-phenylene, 3-fluoro-1,4-phenylene, 3,5-difluoro-1,4-phenylene or pyrimidine-2,5-diyl; Z 4 is independently a single bond, ethylene, carbonyloxy or difluoromethyleneoxy; X 1 and X 2 are each independently hydrogen or fluorine; Y 1 is fluorine, chlorine or trifluoromethoxy; and k is 1 or 2.
10. The liquid crystal composition according to claim 8 , wherein the fourth component is at least one compound selected from the group of compounds represented by formulas (4-1) to (4-18):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
11. The liquid crystal composition according to claim 9 , wherein the fourth component is at least one compound selected from the group of compounds represented by formulas (4-1) to (4-18):
wherein R 1 is alkyl having 1 to 12 carbons, alkoxy having 1 to 12 carbons, alkenyl having 2 to 12 carbons, or alkenyl having 2 to 12 carbons in which arbitrary hydrogen is replaced by fluorine.
12. The liquid crystal composition according to claim 10 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-11).
13. The liquid crystal composition according to claim 11 , wherein the fourth component is at least one compound selected from the group of compounds represented by formula (4-11).
14. The liquid crystal composition according to claim 8 , wherein the ratio of the fourth component is in the range of approximately 5% to approximately 40% by weight based on the total weight of the liquid crystal composition.
15. The liquid crystal composition according to claim 9 , wherein the ratio of the fourth component is in the range of approximately 5% to approximately 40% by weight based on the total weight of the liquid crystal composition.
16. The liquid crystal composition according to claim 1 , wherein the maximum temperature of a nematic phase is approximately 70° C. or higher, the optical anisotropy (25° C.) at a wavelength of 589 nm is approximately 0.08 or more, and the dielectric anisotropy (25° C.) at a frequency of 1 kHz is approximately 2 or more.
17. A liquid crystal display device comprising the liquid crystal composition according to claim 1 .
18. The liquid crystal display device according to claim 17 , wherein an operating mode of the liquid crystal display device is a TN mode, an OCB mode, an IPS mode or a PSA mode, and a driving mode of the liquid crystal display device is an active matrix mode.