Sodium cyanide process
View Patent ↗A process for the production of sodium cyanide crystals comprising; (a) contacting impure hydrogen cyanide and sodium hydroxide in a reactor with mixing for a maximum contact time of about 5 seconds; (b) feeding the resulting mixture to a continuous evaporative crystallizer to produce a slurry of sodium cyanide crystals; (c) passing the slurry of sodium cyanide crystals from the crystallizer over a hot surface to precipitate onto the surface and remove sodium carbonate, and passing said slurry back to the crystallizer; and (d) separating the sodium cyanide crystals from the slurry.
1. A process for the production of sodium cyanide crystals comprising;
(a) contacting impure hydrogen cyanide and sodium hydroxide in a reactor with mixing for a maximum contact time of 5 seconds;
(b) feeding the resulting mixture to a continuous evaporative crystallizer to produce a slurry of sodium cyanide crystals;
(c) passing the slurry of sodium cyanide crystals from the crystallizer via a transfer line and alternating the flow of the slurry between at least two heat exchangers or at least two discrete areas of a hot surface to purposefully precipitate and remove sodium carbonate onto one heat exchanger or one area of the hot surface, while deposited sodium carbonate is cleaned from the other heat exchangers or other areas of the hot surface, and continuously recycling said heated slurry back to the crystallizer after removal of the sodium carbonate; and
(c) separating the sodium cyanide crystals from the slurry.
2. The process of claim 1 wherein the maximum time in the reactor is from about 0.01 seconds to about 2 seconds.
3. The process of claim 1 wherein the time in the reactor is controlled by the rate of feed of HCN into the reactor.
4. The process of claim 1 wherein the hot surface is at a temperature of from about 50° C. to about 250° C.
5. The process of claim 1 wherein the hot surface is cleanable without interruption of the operation of the process.
6. The process of claim 1 wherein the hot surface is one or more heat exchangers.
7. The process of claim 1 wherein the hot surface is comprised of a plurality of surfaces or a plurality of surface areas having a mechanism for directing the slurry of sodium cyanide crystals from one such surface or surface area to another.
8. The process of claim 7 wherein the plurality of surfaces are aligned for operation in parallel or in tandem.
9. The process of claim 7 wherein pressure or temperature differential is used to determine when to direct the slurry of sodium cyanide crystals from the crystallizer from one surface or surface area to another, prior to recycle back to the crystallizer.
10. The process of claim 7 wherein after the slurry of sodium cyanide crystals is directed from one surface or surface area to another, the original surface or surface area is cleaned of precipitated sodium carbonate.
11. The process of claim 1 further comprising
(e) drying the sodium cyanide crystals; and
(f) forming the sodium cyanide crystals into briquettes or other compacted shapes.
12. The process of claim 11 further comprising packaging the briquettes to minimize contact with moisture.
13. The process of claim 1 wherein the sodium cyanide crystals produced are of greater than or equal to 98% purity.
14. The process of claim 1 wherein the sodium cyanide crystals produced are of greater than or equal to 99% purity.
15. The process of claim 1 wherein the maximum time in the reactor is less than 1 second.
16. The process of claim 1 wherein the maximum time in the reactor is from about 0.06 seconds to about 0.1 seconds.